A three-dimensional (3D) graphene foam (GF)/poly(dimethylsiloxane) (PDMS) composite was fabricated by infiltrating PDMS into 3D GF, which was synthesized by chemical vapor deposition (CVD) with nickel foam as template. The electrical properties of the GF/PDMS composite under bending stress were investigated, indicating the resistance of the GF/PDMS composite was increased with the bending curvature. To improve the bending sensitivity of the GF/PDMS composite, a thin layer of poly(ethylene terephthalate) (PET) was introduced as substrate to form double-layer GF/PDMS-PET composite, whose measurements showed that the resistance of the GF/PDMS-PET composite was still increased when bended to the side of PET, whereas its resistance would be decreased when bended to the side of GF. For both cases, the absolute value of the relative variation of electrical resistance was increased with the bending curvature. More importantly, the relative variation of electrical resistance for double-layer GF/PDMS-PET composite can be up to six times higher than single-layer GF/PDMS composite for the same bending curvature. These observations were further supported by the principle of mechanics of material. The 3D GF/PDMS-PET composite also has higher flexibility and environment stability and can be utilized as a strain sensor with high sensitivity, which can find important applications in real-time monitoring of buildings, such as a bridge, dam, and high-speed railway.

The exploration of efficient electrocatalysts for energy conversion is important for green energy development. Owing to their high surface areas and unusual electronic structure, 2D electrocatalysts have attracted increasing interest. Among them, non‐van der Waals (non‐vdW) 2D materials with numerous chemical bonds in all three dimensions and novel chemical and electronic properties beyond those of vdW 2D materials have been studied increasingly over the past decades. Herein, the progress of non‐vdW 2D electrocatalysts is critically reviewed, with a special emphasis on electronic structure modulation. Strategies for heteroatom doping, vacancy engineering, pore creation, alloying, and heterostructure engineering are analyzed for tuning electronic structures and achieving intrinsically enhanced electrocatalytic performances. Lastly, a roadmap for the future development of non‐vdW 2D electrocatalysts is provided from material, mechanism, and performance viewpoints.

It is a challenge to grow perovskite films with large crystalline grains and a full coverage on the surface of an organic compound film by a solution process. Herein, we for the first time introduce environmental‐friendly urea into PbI2 precursor to mediate the perovskite film growth and crystallization on the top of PEODT:PSS for efficient inverted solar cells. This method attains high‐quality perovskite films with large‐size grains of over 2 μm and a full coverage. This enables us to fabricate the inverted perovskite solar cells showing a maximum efficiency of 18.01% with a fill factor of 82.29% and a stabilized efficiency of 17.56%. Infrared spectroscopy and scanning electron microscopy images demonstrate that urea is coordinated with PbI2 to form PbI2 · OC(NH2)2 complex, resulting in large PbI2 flakes by a slow crystallization. The large PbI2 flake with fewer nucleation sites is conducive to forming monolithic perovskite grains. Further investigation indicates that CH3NH3I · PbI2 · OC(NH2)2 complex is formed as an intermediate phase, which retards the crystallization process of the perovskite films. These factors lead to a high‐quality perovskite film with large grain size and excellent crystallinity.

Abstract:Quantum entanglement of two photons created by spontaneous parametric downconversion (SPDC) can be used to probe quantum optical phenomena during a single cycle of light. Harris [Phys. Rev. Lett. 98, 063602 (2007)] suggested using ultrabroad parametric fluorescence generated from a quasi-phase-matched (QPM) device whose poling period is chirped. In the Harris's original proposal, it is assumed that the photons are collinearly generated and then spatially separated by frequency filtering. Here, we alternatively propose using noncollinearly generated SPDC. In our numerical calculation, to achieve 1.2 cycle temporal correlation for a 532 nm pump laser, only 10% -chirped device is sufficient when noncollinear condition is applied, while a largely chirped (50%) device is required in collinear condition. We also experimentally demonstrate an octave-spanning (790-1610 nm) noncollinear parametric fluorescence from a 10 % chirped MgSLT crystal using both a superconducting nanowire single-photon detector and photomultiplier tube as photon detectors. The observed SPDC bandwidth is 194 THz, which is the largest width achieved to date for a chirped QPM device. From this experimental result, our numerical analysis predicts that the bi-photon can be compressed to 1.2 cycles with appropriate phase compensation.