This article reports an experimental investigation into the effect of solid suspension on the viscosity of molten slags. Up to about 20 vol pct of spinel (MgAl 2 O 4 ) particles of three size ranges (fine: 0.10 to 0.21 mm; medium: 0.21 to 0.44 mm; and coarse: 0.44 to 0.99 mm) were added to a CaO-MgOAl 2 O 3 -SiO 2 melt at 1646 (Ϯ10) K. A Brookfield DVIIϩ viscometer was used. The viscosity determined for the solid-free melts was in good agreement with the results of published work. The viscosity for the solid-containing melt was found to increase with the addition of the particles. With more than 10 vol pct solid particles, particularly the fine and the coarse ones, the melt showed an apparent "Bingham" behavior, i.e., the shear stress increased linearly with the shear rate but had a residual shear stress (up to 3 Pa depending on the amount and size of solid added) at zero shear rate. The viscosity of the solid-containing slag, , was found to fit an Einstein-Roscoe type equation, ϭ 0 (1 Ϫ af ) Ϫn , where 0 is the viscosity of the solid-free melt, f is the volume fraction of solid particles in the melt, and a and n are parameters taking the value of 4.24, 3.29, and 3.56 and 1.28, 2.36, and 2.24 for the fine, medium, and coarse particles, respectively, for best fit.
New measurements have been made on the phase equilibria of magnesia-saturated CaO-FeO xSiO 2 slags at 1573 K (1300°C) and an oxygen partial pressure of 10 À9 atm. The thermodynamic behavior of selenium (Se) and tellurium (Te) in the slag and the stability of oxide mineral phases within the slag were examined as a function of slag composition. The measured equilibrium distribution of Se and Te between the slag and the copper showed nonlinear dependence on the slag basicity, reaching maxima at CaO/(CaO + SiO 2 ) ratios of about 0.2 and 1 and a minimum at a ratio of about 0.5. The solubility of the copper oxide in the bulk slag also passed through a minimum value at a ratio of about 0.5. Results from drop-quench experiments confirmed the stability of various oxide solid solution phases at 1573 K (1300°C) that had virtually no solubility for Se and Te. The deduced capacity of the liquid slag for Se was found to be independent of basicity in relatively basic slags, and decreased sharply as SiO 2 replaced CaO in relatively acidic slags.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.