An extended geminal model has been applied to determine the interatomic potential for the X 1 ⌺ g ϩ state of Be 2 . By adopting a (23s, 10p, 8d, 6f, 3g, 2h) uncontracted Gaussian-type basis, the following spectroscopic parameters are obtained:

We report results from close-coupling calculations for homonuclear ultracold collisions between potassium atoms, using the most up-to-date Born-Oppenheimer potential curves. The present study includes both of the bosonic isotopes 39 K and 41 K. The s-wave scattering lengths as functions of the magnetic field strength for collisions between atoms in identical and different hyperfine states are obtained. Several Feshbach resonances are located and characterized for both isotopes. Comparison with experiments, where such data are available, show excellent agreement. We also study weakly bound molecular states of the K 2 molecule in close relation to the calculated Feshbach resonances. Another objective of the present work is to study inelastic collisions in which the hyperfine states of the colliding atoms are changed. From this type of calculation we obtain transition rates as functions of the magnetic field strength. Finally, we discuss how such transition rates might be of importance for experimental work.

The N2 1sB 2 Xd dispersed fluorescence from photon excited N2 molecules has been measured in the 19–34 eV excitation range, where our theory predicts the existence of non-Rydberg doubly excited resonances which autoionize in the sub-fs regime into the N2 1 B2S1u ionic state. The experimentally deduced vibrational branching ratios sy0 ­ 1dysy0 ­ 0d revealed five prominent features, four of which could be identified as such doubly excited resonances based on the lowest order of the many-body perturbation theory. [S0031-9007(96)00230-X]

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We present the results of an experimental and theoretical study of the electronically excited (1) 3 + g state of 87 Rb 2 molecules. The vibrational energies are measured for deeply bound states from the bottom up to v = 15 using laser spectroscopy of ultracold Rb 2 Feshbach molecules. The spectrum of each vibrational state is dominated by a 47-GHz splitting into 0 − g and 1 g components caused mainly by a strong second-order spin-orbit interaction. Our spectroscopy fully resolves the rotational, hyperfine, and Zeeman structure of the spectrum. We are able to describe this structure to the first order using a simplified effective Hamiltonian.