Grounded the method for predicting of trace elements (TE) and heavy metals (HM) content in the soil system of different genesis were examined on the example of soils in different natural-climatic zones of Ukraine, contaminated soils in Kharkiv, Donetsk and Lugansk regions, and intensive fertilizer (organo-mineral, organic and mineral system of fertilizers) of soils in Kiev, Kharkiv, Poltava and Lviv region. In the developed methodical approach by using the parameters indicators of the energy state of the soil (calorific value of humus, the reserves of energy in the soil layer of 0–20 cm) using mathematical models and the spread of the algorithm of the method on other soil types of a particular natural-climatic zone in the conditions of technogenic pollution and technological load is predicted the TE and/or HM content in soils of different types, which ensures the rapidity of the assessment and improve the accuracy of the trace element status prediction, energy and humus state of soils of different genesis with the identification of soils ecological differences to predict their quality by assessment of ecological functions for the ranking of energy intensity indicators of the soil. Scientific elaboration of a method for predicting levels of chemical elements in soils of different types on the natural environment, the effects of man-made pollution and technological load, should be used in the environmental regulation of the TE content and normalization of loads (technogenic, technological) on the soil system, agroecology on issues of organic farming, bioenergy and energy of soil formation; diagnosis, estimation, prediction of humus quality and the of TE status and the danger of excessive accumulation of HM in the soil for indicators of the energy state; the effective environmental management of soils as in natural conditions, and the influence of various anthropogenic factors, taking into account their ecological functions; in research practice – for system research of natural components of the biosphere, the assessment of carbon sequestration in soils and assess of their quality. Distinctive features and advantages of the proposed elaboration in comparison with known methods and approaches are: greater predictability of energy and trace element status, humus and ecological state of the soil as a whole to prevent the degradation of soil organic matter and reduction of risks of influence of HM technogenic pollution; rapidity of obtaining and improving the accuracy of the predictions of the HM and TE content in the soil; universality way to suitability of the method for all soil types in different climatic zones; stimulating further research in the field of energy of soil formation and solution of practical tasks of conservation and restoration of soils functions, identification optimal energy cost and taking into account the ecological functions of soil certain type.
Grounded the new elaborated method for predicting of trace elements (TE) and heavy metals (HM) content in the soils of different genesis, which was elaborated by analysis the indicators parameters of their organic matter and energy characteristics in different natural-climatic zones of Ukraine, also of contaminated and intensive fertilizer soils. The method aims for the assessment of soils ecological-energy state due to the installation of the new natural relations of indicators humus, energy and elemental status of soils of different types, as a result, expanding the range of diagnostic indicators with identifing their paired combinations and simultaneously increasing of informativeness, accuracy, express testing of chemical elements (TE, HM) predicting levels, energy and humus state of soils to predict and ecological regulation of their quality. The essence of the elaborated utility model – by the identify of new patterns of soil properties indicators and receive four matching pairs of humus (CGA/CFA, Ctotal), elemental and energy state (calorific value of humus, the reserves of energy in the soil layer of 0–20 cm) as soil indicators with the using of mathematical-statistical analysis of the obtained regression equations for the accurate determination is predicted the TE and HM content in soils of different types of background conditions, with the distribution algorithm of the method for different soil types in certain climate zones in the conditions of technogenic pollution and technological load, risk and the presence of man-made pollution to make timely management decisions. Elaborated method ensures the rapidity of the assessment and improves the accuracy of the TE/HM status prediction, energy and humus state of soils of different genesis with the identification of soils ecological differences to predict their quality by assessment of ecological functions for the ranking of energy intensity indicators of the soil. The method is applicable in the environmental regulation of TE and HM content, regulation of the loads (technogenic, technological) on a soil system, agroecology to address issues of biological agriculture, bio-energy and energy of soil formation; monitoring the quality of humus and the status TE and the dangers of excess accumulation of HM, in the soil humus indicators and /or energy state; efficient environmental management of soils, both in background conditions and with different anthropogenic impacts and in the research practice. Grounded the method was examined on the of soils simples in different natural-climatic zones of Ukraine, contaminated soils in Kharkiv, Donetsk and Lugansk regions, and intensive fertilizer (organo-mineral, organic and mineral system of fertilizers) of soils in Kiev, Kharkiv, Poltava and Lviv region.
The method for predicting the levels of the easily hydrolysable nitrogen content in soils of various types of Polesie, Forest-steppe and Steppe climatic zones of Ukraine for the assessment of soil quality due to the background conditions, the influence of technological load (for the application of organo-mineral, organic and mineral fertilizer systems), and risk or influence of technogenic pollution by heavy metals (HM) is grounded. In the elaborated methodical approach is obtained a regression equation by the determination of new correlations of soil energy intensity indices (the calorific value of humus, soil energy reserves in a layer up to 20 cm) in conjunction with the humus state and the use of mathematical and statistical analysis for determining the value of easily hydrolysable nitrogen with the ability to predict the quality of soils of various genesis, with the further extension of the method algorithm for different soil types, climatic zones due to technogenic HM pollution and technological load. The technical result of the elaborated method: by improving the determination of the levels of the easily hydrolysable nitrogen content in soils of different genesis for the evaluation of their quality by identifying the most correlated, diagnostically applicable integral basic indicators of soil properties, which allow the informativeness to make managerial decisions and to predict the quality of soils of different genesis in the content of easily hydrolysable nitrogen, as a biogenic element, due to the background conditions and anthropogenic loads with increased accuracy, speed and informativeness. Elaborated method can find application in the ecological standardization of the content of biogenic macroelements, the normalization of loads (technogenic, technological) on the soil system, agroecology for solving the problems of organic agriculture, bioenergy and energy of soil formation; diagnostics, evaluation, forecasting of the soils nitrogen systems state; the quality of humus and macroelement status of soils on indicators of ecological and energy status; effective ecological management of soils due to the background conditions, as well as for various anthropogenic influences and in scientific research for the investigating of biogeochemistry and biogenic macroelements of soil cover. Separate provisions of the elaborated method became an integral part of the proposals on adaptation to the Nitrate Council Directive 91/676 / EEC of 12.12.1991 on the protection of water from pollution caused by nitrates from agricultural sources, as amended by Regulation (EC) № 1882/2003 Cross Nitrogen Balances Handbook. Prospective directions of research in the field of diagnostics, assessment, forecasting of the state of soils nitrogen systems and the normalization of the elemental composition quality, in particular, the content of nutrient nitrogen are determined. In order to overcome the biogenic pollution (excessive accumulation of nitrogen compounds) in the environment (plants, waters), the normalization of nitrogen content in soils of different genesis should include: a) determination of the maximum permissible levels of mobile mineral forms of nitrate nitrogen by the elaboration of environmental requirements for nitrates contamination with plant products; b) normalization of the content of labile easily hydrolysable nitrogen and / or a dose of nitrogen fertilizers in conditions of sufficient and excessive moistening, considering the rapid processes of transformation of nitrogen compounds in soils; c) normalization of the soil nitrogen mineral compounds content in conditions of insufficient moistening and slowing down the processes of circulation of nitrogen compounds of soils. Distinctive features and advantages of the proposed elaboration in comparison with known methods and approaches are: 1) the express obtain of the accurate projected levels of easily hydrolysable nitrogen as a nutrient in the soil with the improving the accuracy of soil diagnosis by the use of the basic integrated indicators; 2) providing opportunity for greater efficiency of forecasting data on the functioning of the nitrogen systems of different genesis soils, quality, environmental and energy state of soils due to the background conditions and anthropogenic loads while minimizing the cost of material resources; 3) empowerment of the user in determination of the easily hydrolysable nitrogen content in the soil without extensive chemical analysis by the choice of regression equations, based on the use of baseline soil properties of a particular type and subtype according to the available information; 4) versatility of the method by the suitability of detected dependencies of the proposed method for all soil types and subtypes, climatic zones and contaminants.
The method for prediction of productive functions of soils, according to their macronutrient status, is grounded on the example of the total concentrations of nitrogen as biogenic macronutrient in different soil types of Polesie, Forest-Steppe and Steppe climatic zones of Ukraine including soils contaminated by heavy metals and fertilized (organic-mineral, organic and mineral system of fertilizer) soils. In the elaborated methodical approach the productive function (fertility) of different genesis soils forecasts by establishing new relationships of total nitrogen content with a humus calorific value, the energy reserves of the soil in layer up to 20 cm, the application of mathematical-statistical analysis. For example, according to the total nitrogen content as a biogenic macronutrient in accordance with the fixed gradations, with a further extension of the method algorithm for different soil types of climatic zones by the influence of technogenic pollution and technological load. The technical result of the elaborated method is to improve the known method of soil fertility prediction, considering their macronutrient status, by the selective choice of the most correlation associated, diagnostics capable of integral indicators of the energy and nitrogen status of the soil, which enhances the informativeness, accuracy and quick speed forecasting of production and ecological functions of different genesis soils with the identification of differences in ecological condition of soils for prediction and regulation of their quality. The elaborated methodological approach may find application in the assessment and ecological standardization of soil quality by chemical elements content, regulation of loads (technogenic, technological) on a soil system, in agroecology by investigating the question of soil fertility monitoring, lands certification of different purpose and use; organic farming, bioenergy and energy of soil formation; diagnosis, evaluation, determination of quality of humus and the state of the chemical elements; in environmental management of soils both for background conditions and different anthropogenic impacts and in research practice – investigating the biogeochemistry and nutrient macronutrients of the soil cover. Distinctive features and advantages of the proposed elaboration in comparison with known methods and approaches are: 1) express obtain of the accurate by predicted levels of total nitrogen content as a nutrient in the soil with the improving of the soil diagnosis accuracy by establishing some interconnected diagnostically suitable indicators of soils humus substances and nitrogen systems functioning, the direction of the mobilization and immobilization of nutrients (C, N) processes, the humification-mineralization and energy intensity of soils, including the negative impacts of anthropogenic pressures and degradation processes; 2) providing the opportunity for increasing effectiveness of predicting data on the functioning of the nitrogen systems of different genesis soils, environmental and energy state of soil and level of their potential fertility due to the background conditions, the application of different fertilization systems, and risk the availability of heavy metals pollution while minimizing the consumption of material resources; 3) expansion of the user’s ability to determine the total nitrogen content in the soil without long-term chemical analytical research due to the choice of regression equations obtained on the basis of the use of baseline soil properties of a certain type and subtype, according to available information; 4) versatility due to suitability of installed dependencies of the proposed method for all soil types and subtypes, climatic zones and contaminants.
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