A number of symmetric, asymmetric and complex esters of 2,2,5,5-tetramethylolcyclopentanol and 2,2,6,6-tetramethylolcyclohexanol were synthesized, their physicochemical, viscosity-temperature and thermo-oxidative properties were studied. With the addition of these esters to hydrotreated diesel fuels 0.004% it was possible to significantly improve the operational properties of fuels: to increase thermal oxidative stability, flash point and lower pour point. Proceeding from these results, the esters of cyclic polyatomic alcohols are recommended as complex additives to diesel fuels
The esters of oxypropylated 2,2,6,6-tetrametylolcyclohexanol with aliphatic monocarboxylic acids C -C4 8have been synthesized. Their physicochemical, viscosity-temperature, thermal-oxidative and lubricating propertieswere studied. It was determined that they have good operational properties, they meet requirementsfor high-temperature lubricating oils and are recomended as the new base or components to other lubricating oils.
Complex esters of 2.5,5.5-tetrametylolcyclopethane with heptanedioic and hexanoic acids, as well as methyl and 2-ethylhexyl alcohols have been synthesized and studied. Few compositions have been obtained adding these esters to the industrial ones of 5-20 % diisooktyl sebacylic. It was defined that exploitation characteristics of these compositions are significantly higher than those of DOS: viscosity index, flash point, thermal oxidative stability and lubricating characteristics. Based on these parameters, it is recommended to use in the future these compositions in the preparation of aircraft oils of gas-turbine engines instead of DOS esters.
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