We report the synthesis of Co 2+ substituted Mg-Cu-Zn ferrite via citrate gel combustion process and thereby its structural, transport, and magnetic properties for the use in electromagnetic energy absorption application. The polycrystalline ferrite system is investigated by interplay of stoichiometric composition with Mg 0.25-x Co x Cu 0.25 Zn 0.5 Fe 2 O 4 (0 ≤ x ≤ 0.25). Structural investigations using X-ray diffraction (XRD) and selected area electron diffraction (SAED) reveal the formation of spinel structure with linear growth of lattice constant due to Co 2+ substitution. The microstructural analysis (TEM and SEM) depicts the dense microstructure with the average grain size of 0.42-1.25 µm. The elemental analysis (EDS) confirms the elemental composition of the as-prepared ferrite with respect to the initial concentrations of the synthetic composition used. The observed variations in initial permeability ( i ) and magnetic moment ( ) are explained based on deviation in saturation magnetization ( s B n M ), anisotropy constant ( 1 K ), density values, and exchange interaction. The temperature dependence of DC resistivity confirms the semiconducting behavior of the as-prepared ferrite material, with an increase in the DC resistivity by an incorporation of cobalt. Furthermore, the effects of adding Co 2+ on the Curie temperature, frequency dependent dielectric properties of the ferrite material are also discussed.
We report on the electromagnetic properties of Co2+ substituted spinel MgCuZn ferrites developed via a facile molten salt synthesis (MSS) route. The choice of synthesis route in combination with cobalt substitution led to strong electromagnetic properties such as high saturation magnetization (i.e., 63 emu/g), high coercivity (17.86 gauss), and high initial permeability (2730), which are beneficial for the multilayer chip inductor (MLCI) application. In a typical process, the planned ferrites were synthesized at 800 °C using sodium chloride as a growth inhibitor, with dense morphology and irregularity in the monolithicity of the grains. The compositional analysis of as-prepared ferrite confirms the presence of desired elements with their proportion. The crystallite size (using X-ray diffraction (XRD) analysis) for different samples varies in the range of 49–51 nm. The scanning electron microscopy (SEM) and transmission electron microscopy (TEM) analysis showcases the compact morphology of the developed samples, which is typical in the ferrite system. The dielectric properties (dielectric-loss and dielectric-constant) in the frequency range of 100Hz–1MHz suggest normal dielectric distribution according to interfacial polarization from Maxwell–Wagner. From the developed ferrites, upon comparison with a low dielectric loss with high permeability value, Mg-Cu-Zn ferrite with Co = 0.05 substitution proved to be a stronger material for MLCIs with high-performance applications.
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