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Cationic transference numbers and conductance data of KSCN and Me4NSCN in methanol (‐15°C to + 25°C), KSCN in ethanol (‐5°C to + 25°C) and propanol (+ 10°C and +25°C), Me4NClO4 and Et4NClO4 in acetonitrile (‐35°C to +25°C) were determined at electrolyte concentrations from 10−3 to 10−2 mol · kg−1. The transference numbers obtained by a moving boundary method were corrected for the changes of the calibration volume resulting from anodic reactions, conductance of the solvent and Joule heating. The data are discussed on the basis of transport equations which take into account short range interactions in the ion distribution functions.

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