A database of surface Antarctic snow isotopic composition is constructed using available measurements, with an estimate of data quality and local variability. Although more than 1000 locations are documented, the spatial coverage remains uneven with a majority of sites located in specific areas of East Antarctica. The database is used to analyze the spatial variations in snow isotopic composition with respect to geographical characteristics (elevation, distance to the coast) and climatic features (temperature, accumulation) and with a focus on deuterium excess. The capacity of theoretical isotopic, regional, and general circulation atmospheric models (including "isotopic" models) to reproduce the observed features and assess the role of moisture advection in spatial deuterium excess fluctuations is analyzed.

Ice-core records of climate from Greenland and Antarctica show asynchronous temperature variations on millennial timescales during the last glacial period. The warming during the transition from glacial to interglacial conditions was markedly different between the hemispheres, a pattern attributed to the thermal bipolar see-saw. However, a record from the Ross Sea sector of East Antarctica has been suggested to be synchronous with Northern Hemisphere climate change. Here we present a temperature record from the Talos Dome ice core, also located in the Ross Sea sector. We compare our record with ice-core analyses from Greenland, based on methane synchronization, and find clearly asynchronous temperature changes during the deglaciation. We also find distinct differences in Antarctic records, pointing to differences in the climate evolution of the Indo-Pacific and Atlantic sectors of Antarctica. In the Atlantic sector, we find that the rate of warming slowed between 16,000 and 14,500 years ago, parallel with the deceleration of the rise in atmospheric carbon dioxide concentrations and with a slight cooling over Greenland. In addition, our chronology supports the hypothesis that the cooling of the Antarctic Cold Reversal is synchronous with the Bølling–Allerød warming in the northern hemisphere 14,700 years ago

In the framework of the International Trans-Antarctic Scientific Expedition (ITASE) programme, France and Italy carried out a traverse along one west-east and two north-south transects in East Antarctica from November 2001 to January 2002. Eighteen shallow snow-firn cores were drilled, and surface snow samples were collected every 5 km along the traverse. Firn temperatures were measured in boreholes down to 30 m. The cores were analyzed for radioactivity to obtain snow accumulation-rate data. The surface snow samples were analyzed for d 18 O to correlate isotopic values with borehole temperatures. Multiple regression analysis shows a global near-dry-adiabatic lapse rate and a latitudinal lapse rate of 1. 05˚C (˚lat. S) -1 , in the Dome C drainage area. Analysis of firn temperatures reveals a super-adiabatic lapse rate along the ice divide between Talos Dome and the Southern Ocean coast, and in some sectors along the ice divide between the Astrolabe Basin and D59. Snow accumulation rates and firn temperatures show warmer temperatures and higher accumulation values close to the ice divides extending from Talos Dome and Dome C to the SouthernOcean. The spatial pattern of data is linked with a katabatic-wind-source basin and moisture-source region.

In the framework of the PNRA–ITASE (Programma Nazionale di Ricerche in Antartide–International Trans-Antarctic Scientific Expedition) project, during the field season 1998/99, surface snow (1m cores and pits) and shallow firn cores (10–50m) were collected along a traverse from Terra Nova Bay (northern Victoria Land) to Dome C (East Antarctic ice sheet). Results of chemical, tritium and stable-isotope composition are presented here for the 1 m cores, some snow pits and the first 2 mof some shallow firn cores. the δ18O values show a regular trend with altitude, and the regression line between δ18O and surface temperature is δ18O = 0.99T (˚C) – 0.67. Primary aerosol components such as Na+, Cl–, Ca2+,Mg2+ and K+ show high concentrations decreasing with increasing altitude in the first 250–350km from the coast. At greater distances, concentrations of these species remain more constant. NO3– concentration shows an irregular profile with a progressive decreasing trend as altitude increases. Non-sea-salt (nss) SO42– concentration decreases up to about 250 km from the coast, increases 250–770 km from the coast and remains relatively constant in the most remote stations. Methanesulphonate (MSA) concentration shows high variability. the MSA/nssSO42– ratio exhibits a decreasing trend 250–550km from the coast. With increasing distance, the ratio shows moderate oscillations. nssCl– concentration shows a progressive increase as distance from the coast increases, in agreement with the increasing influence of HCl on the Cl– budget of the inland Antarctic atmosphere. Post-depositional re-emissions of Cl– and NO3– were found at stations characterized at the surface by long-term accumulation hiatus (wind crusts). the chemical-species distribution is consistent with the presence in the studied area of local and long-range transport processes, post-depositional effects and snow-accumulation variations observed along the traverse.

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