We have measured the growth of liquid films of Ar adsorbed on well defined arrays of microscopic linear wedges sculpted on thin Si wafers and on a stainless steel disk. On these patterns, a clear cross-over from a planarlike to a geometry dependent growth behavior is observed. This crossover is found to depend on the characteristic wedge size. Near liquid-vapor bulk coexistence, the film mass is observed to diverge as a power law of the chemical potential difference from saturation with an exponent in very good agreement with the value of -2 expected for a linear wedge. This exponent is not affected by the opening angles of the wedges. All these findings are in accordance with a recent scaling theory.

The electron drift mobility has been measured in a wide range of temperatures and densities in neon gas and saturated vapor. The "zero-Geld" density-normalized mobility poS exhibits a strong density dependence, which cannot be accounted for by the existing multiple-scattering theories. The data, however, can be well 6tted by assuming a density dependence in the e-Ne scattering cross section.

Capillary condensation in nanoporous anodic aluminum oxide presenting not interconnected pores with controlled modulations is studied using adsorption experiments and molecular simulations. Both the experimental and simulation data show that capillary condensation and evaporation are driven by the smallest size of the nanopore (constriction). The adsorption isotherms for the open and closed pores are almost identical if constrictions are added to the system. The latter result implies that the type of pore ending does not matter in modulated pores. Thus, the presence of hysteresis loops observed in adsorption isotherms measured in straight nanopores with closed bottom ends can be explained in terms of geometrical inhomogeneities along the pore axis. More generally, these results provide a general picture of capillary condensation and evaporation in constricted or modulated pores that can be used for the interpretation of adsorption in disordered porous materials.