L. A. Glinskaya scite author profile

we established the following: l) Tautomerism. In the crystals of all compounds, the molecules exist in the asymmetric tautomeric form. The ring proton is located near the donor (II) and far from the acceptor (IV) substituent. 2) Conformation. The substituents are insignificantly inclined to the ring plane. Only (III) is not flat. The bis-nitrotriazolyl molecules are centrosymmetric (V) or pseudocentrosymmetric (VI). 3) Molecular interaction. The ring proton participates in strong hydrogen bonds in the crystals of all compounds. All triazole molecules, except (V), interact by N-H ... N hydrogen bonding. The triazole ring in (V) is connected with water molecules by N-H ... O bonds. Vander Waals forces represent the main bond type in this crystal.

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L. A. Glinskaya

Crystal structure investigation of ternary molybdates Li3Ba2Ln3(MoO4)3 (Ln=Gd, Tm)

Syntheses of mixed-ligand coordination compounds Sm(2,2′-bipy)(S2CN(C2H2))2 and SmPhen(S2CN(C2H5)2)3. crystal structure of Sm(2,2′-bipy)(S2CN(C2H5)2)3

Synthesis and crystal structure of new complex oxides K10M2+Mo7O27 (M2+ = Mg, Mn, Co)

Phase formation in the Rb2MoO4-Er2(MoO4)3-Hf(MoO4)2 system and the crystal structure of new triple molybdate Rb5ErHf(MoO4)6

Synthesis and crystal and molecular structure of mixed-ligand compounds Eu(S2CN(C2H5)2)3(2,2′-Bipy) and Eu(S2CN(C2H5)2)3(1,10-Phen)

Luminescence properties of complexes Ln(Phen)(C6F5COO)3 (Ln = Tb, Eu) and Ln(C6F5COO)3 · nH2O (Ln = Tb, n = 2; Ln = Eu, n = 1). Structures of the [Tb2(H2O)8(C6F5COO)6] complex and its isomer in the supramolecular compound [Tb2(H2O)8(C6F5COO)6] · 2C6F5COOH

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Composition and crystal structures of double molybdates of uni- and bivalent metals

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