Recently emerged ionic thermoelectric conversion with the Soret effect is advantageous in providing large thermopower on the order of ≈1-10 mV K −1 , but the origin of the large thermopower and the methodology of attaining superior thermoelectric performances are yet to be disclosed. Here, key parameters and their optimization for outstanding thermoelectric responses with polystyrene sulfonic acid (PSS-H) are unveiled. It is found that the thermo-diffusion of water boosts proton transport, playing a key role in obtaining large ionic thermopower by promoting unidirectional migration of protons from a hotter to colder side. When graphene oxide (GO) embedded in PSS-H is aligned along the transport direction of protons and water, their diffusion along the in-plane direction of GO is promoted, enlarging both ionic thermopower and ionic electrical conductivity. PSS-H containing 3 wt% GO possesses extremely large ionic power factors up to 1.8 mW m −1 K −2 and ionic figure-of-merits up to 0.85 at 23 °C. This study provides not only preeminent thermoelectric performances based on ion transport but also identifies the influence of the key parameters on thermoelectric properties, suggesting controllability of thermo-diffusion of ions depending on inclusions in base materials, which will draw numerous subsequent research with their alterations.

This paper describes the manufacturing method and properties of a superalloy as a gas turbine blade material and a thermal barrier coating to protect it. The development process of superalloy and characteristics of each casting method were introduced. In particular, the single crystal superalloys were analyzed for creep and tensile properties with temperature according to chemical composition. In addition, the theories of creep life prediction models were summarized and comparative analysis was performed. Finally, the manufacturing processes of thermal barrier coatings were introduced, and the characteristics and effects of mechanical, thermal, and durability characteristics of each manufacturing process are described. We believe that this comprehensive review will help not only the gas turbine industry/community, but also material scientists, measurement physicists/engineers, and theorists interested in superalloys and high-temperature ceramics.

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