The manganese(II)‐palladium(II)‐sulfide complex [MnCl2(μ3‐S)2Pd2(dppp)2] (2) was prepared from the reaction of [PdCl2(dppp)] with [Li(N,N'‐tmeda)]2[Mn(SSiMe3)4] (2) in a 2:1 ratio under mild conditions. The new trimethylsilylthiolate complex [Pd(dppp)(SSiMe3)2] (3) was synthesized from the reaction of [Pd(dppp)(OAc)2] with two equivalents of Li[SSiMe3]; this was then used in a reaction with [Mn(CH3CN)2(OTf)2] to form the manganese(II)‐palladium(II)‐sulfide cluster [Mn(OTf)(thf)2(μ3‐S)2Pd2(dppp)2]OTf (4).