Lactic acid is a renewable and versatile chemical for food, pharmaceuticals, cosmetics, and other chemicals. Lactic acid can be produced from biomass‐derived dihydroxyacetone. However, selective and recyclable water‐tolerant acid catalysts need to be developed for the specific production of lactic acid. Here we show that the MIL‐101(Al)−NH2 metal‐organic framework (MOF) is a water‐tolerant and selective solid Lewis acid catalyst for dihydroxyacetone isomerization to lactic acid. The Lewis acidic MIL‐101(Al)−NH2 catalyst promoted a high lactic acid selectivity of 91 % at 96 % dihydroxyacetone conversion at 120 °C in water. The reaction proceeded by temperature and/or MIL‐101(Al)−NH2 MOFs mediated dihydroxyacetone dehydration to pyruvaldehyde. Subsequently, the MIL‐101(Al)−NH2 facilitated rehydration of the pyruvaldehyde to lactic acid. The Lewis acidic MIL‐101(Al)−NH2 catalyst was stable and reusable four times without any decrease in catalytic performance.
The production of fuels and chemicals from lignin can mitigate greenhouse gas emissions generated by fossil fuel processing. Current upgrading pathways for converting lignin into useful chemicals require multiple steps...
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.