The literature dealing with the high-temperature behavior of inorganic nitrates and nitrites has been critically reviewed. Values of (G'f-H~98)/T of the reactants and products of the decomposition reactions were calculated and have been tabulated from 298 K up to as high a temperature as possible. Equilibrium constants and partial pressures were tabulated. Auxiliary data on phase transitions and densities have also been included. Qualitative information about the thermal decomposition of the salts is reviewed.

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Collision theory considerations, the temperature coefficient of energy of activation, and relative rates of ion-ion and ion-molecule reactions... 50 3. The dependence of the specific velocity constant on the dielectric constant of the solvent for ion-ion reactions.

The literature dealing with the high-temperature behavior of inorganic sulfates has been critically reviewed. Free energy functions of reactants and products of the decomposition reactions were calculated and have been tabulated from 298°K up to as high a temperature as possible. Free energy functions, equilibrium constants of reactions, and partial pressures of gaseous components were tabulated. Auxiliary data on phase transitions, densities, and kinetics of chemical decomposition have also been included.