The pursuit of high reversible capacity and long cycle life for rechargeable batteries has gained extensive attention in recent years, and the development of applicable electrode materials is the key point. Herein, thanks to the preintercalation of lithium ions, a stable and highly conductive nanostructure of V2C MXene is successfully fabricated via a facile self‐discharge mechanism, which provides open spaces for rapid ion diffusion and guarantees fast electron transport. Taking the prelithiated V2C as electrode, an outstanding initial coulombic efficiency of 80% and an impressive capacity retention of ≈98% after 5000 charge/discharge cycles are achieved for lithium‐ion batteries. Especially, it demonstrates a fascinating reversible capacity of up to 230.3 mA h g−1 at 0.02 A g−1 and a long cycling life of 82% capacity retention over 480 cycles in the hybrid magnesium/lithium‐ion batteries. In addition, the Mg2+ and Li+ ions cointercalation mechanism of the prelithiated V2C is elucidated through ex situ X‐ray diffraction and X‐ray photoelectron spectroscopy characterizations. This work not only offers an effective approach to compensate the large initial lithium loss of high‐capacity anode materials but also opens up a new and viable avenue to develop promising hybrid Mg/Li‐storage materials with eminent electrochemical performance.
The
effective removal of chlorine ion from the desulfurization
slurry is of great significance to the stable operation of the desulfurization
system. Modified fly ash hydrotalcites were prepared by alkali/acid-combined
roasting and microwaving and used as an adsorbent for chlorine ion
in desulfurized wastewater. The specific surface area and porosity
of different adsorbents were analyzed by X-ray diffraction (XRD) and
scanning electron microscopy (SEM). The impacts of pH, temperature,
adsorbent dosage, and adsorption shaking time on adsorption performance
were investigated. Results showed the alkali-combined roasting-modified
fly ash hydrotalcite has the optimum removal effect on Cl–. The optimal adsorption performance was achieved when the pH was
8, the adsorption temperature was 60 °C, the mass concentration
of adsorbent was 10 g/L, the adsorption shaking time was 180 min,
and the removal percentage of Cl– was 68.1%. The
adsorption isotherm was consistent with the Langmuir isotherm model,
and the adsorption saturation was 694.4 mg/g, which belonged to monolayer
adsorption.
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