As compared to the widely studied linear‐type polyisocyanides (PICs), the development of cross‐linked PICs has not attracted much attention, and their applications in electrochemical fields are scarcely reported by far. Herein, a type of novel fluorene‐based isocyanide monomer (BIF), which bears two isocyano (─NC) groups, is successfully synthesized via Hofmann method with 9, 9‐bis (4‐aminophenyl) fluorene as the precursor. Corresponding fluorene‐based, cross‐linked PIC derivative (PBIF) is successfully prepared by Ni2+‐catalyzed polymerization of BIF. Chemical structure, elemental composition, accumulation state, thermal stability, microstructure, porous characteristics, and specific surface area of PBIF are characterized. NO2− and SO32− electrochemical responses of the modified glassy carbon electrode (PBIF/CS/GCE), which is fabricated with PBIF as the active material and chitosan (CS) as adhesive agent, is systematically analyzed here. Experimental results show that PBIF/CS/GCE exhibits strengthened NO2−/SO32− electrochemical response, suggesting that PBIF has a potential application prospect as novel non‐conjugated polymer‐based NO2−/SO32− electrochemical probing material.

No abstract

As the pollution by heavy metal lead ion (Pb 2+ ) and nitrite (NO 2 − ) is becoming increasingly severe, the development of probes for hazardous Pb 2+ /NO 2 − is of great practical significance. Most of the reports regarding Pb 2+ /NO 2 − electrochemical probes are based on the involvement of active modifiers that can facilitate the detection of these two pollutants separately, and the active modifier for promoting both Pb 2+ /NO 2 − electrochemical probing has not been reported yet. Herein, by selecting cross-linked polyfluoreneisocyanide (PBIF) and vanillin/furfurylamine-based biomass benzoxazine (Va-Bz) as the starting substrates, a polyisocyanide derivative (PBIF-Va) with various N/O-containing motifs (amide, imine, tertiary amine, and phenolic −OH) was prepared by solidstate benzoxazine-isocyanide chemistry (ssBIC) postmodification. The elementary properties of PBIF-Va, such as the chemical structure and microscopic morphology, were characterized. The modified glassy carbon electrodes (GCEs) with PBIF-Va as the key modifier, PBIF-Va/Nafion/GCE and PBIF-Va/chitosan (CS)/GCE, were prepared, and their electrochemical response toward Pb 2+ and NO 2 − was investigated here. Experimental results showed that compared with the precursor (PBIF)-containing electrodes (PBIF/Nafion/GCE and PBIF/CS/GCE), the modified electrodes with PBIF-Va as the modifier (PBIF-Va/Nafion/GCE and PBIF-Va/CS/GCE) exhibited stronger electrochemical responses toward both Pb 2+ and NO 2 − , and the corresponding detection limits reached 0.054 μM (for Pb 2+ ) and 0.38 μM (for NO 2 − ), respectively.