Nitrate reductases (NRs) are molybdoenzymes that reduce nitrate (NO3−) to nitrite (NO2−) in both mammals and plants. In mammals, the salival microbes take part in the generation of the NO2−...
Here, we report the nitric oxide dioxygenation (NOD) reactions of NiIII-peroxo, [(12-TMC)NiIII(O22−)]+ (NiIII-O22−, 1), and CoIII-peroxo, [(12-TMC)CoIII(O22−)]+ (CoIII-O22−, 2), complexes bearing N-tetramethylated cyclam (TMC) ligands. The reaction of complex 1...
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