The ORCID identification number(s) for the author(s) of this article can be found under https://doi.org/10. 1002/smll.201904248. Switchable structured adhesion on rough surfaces is highly desired for a wide range of applications. Combing the advantages of gecko seta and creeper root, a switchable fibrillar adhesive composed of polyurethane (PU) as the backing layer and graphene/shape memory polymer (GSMP) as the pillar array is developed. The photothermal effect of graphene (under UV irradiation) changes GSMP micropillars into the viscoelastic state, allowing easy and intimate contact on surfaces with a wide range of roughness. By controlling the phase state of GSMP via UV irradiation during detachment, the GSMP micropillar array can be switched between the robust-adhesion state (UV off ) and low-adhesion state (UV on). The state of GSMP micropillars determines the adhesion force capacity and the stress distribution at the detaching interface, and therefore the adhesion performance. The PU-GSMP adhesive achieves large adhesion strength (278 kPa), high switching ratio (29), and fast switching (10 s) at the same time. The results suggest a design principle for bioinspired structured adhesives, especially for reversible adhesion on surfaces with a wide range of roughness. www.advancedsciencenews.com
Inspired
by
the nanoconcave top of epidermal cells on tree frogs’ toe pads,
an array of composite micropillars with nanopits on the surface (CPp) has been designed. Polystyrene (PS) nanoparticles are mixed
with polydimethylsiloxane (PDMS) and serve as the template for nanopits
on the PS/PDMS composite micropillars. CPp shows much larger
wet adhesion compared to the arrays of micropillars without nanopits.
Under a certain loading force, most of the liquid between CPp and the counterpart surface is squeezed out, so the liquid that
remained in nanopits forms multiple nanoscale liquid bridges within
the contact area of a single micropillar. Moreover, a large loading
force could squeeze part of the liquid out of nanopits, resulting
in the suction effect during the pull-off. The multiple liquid bridges,
the suction effect, and the solid direct contact thus contribute to
strong wet adhesion, which could be ∼36.5 times that of tree
frogs’ toe pads. The results suggest the function of nanoconcaves
on the toe pad of tree frogs and offer a new design strategy for structured
adhesives to gain strong wet adhesion.
The investigation of the surface energy parameters of photovoltaic materials highlights the wetting coefficient as a dominant dynamic for spontaneous Voc gain.
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