Cadmium (Cd) is a non-essential and harmful element to humans. Cadmium contamination is a serious issue for human health, especially in densely populated agroecology areas. In this study, the investigation of an agroecology area was conducted to gain insight into the relationship between Cd in wheat and soil and then evaluate the Cd total risk for human health. The soil samples and their matching wheat samples, underground water samples, and atmospheric deposition (air) samples were collected from a wheat-growing area in an agroecology plain. The cadmium concentration in the four types of media, in order, was air > soil > wheat > water. The mean concentration of the geoaccumulation index (Igeo) showed that the total Cd in soil (Cd-T) and Cdair reached a mild and moderate pollution level. The results of the correlation and principal component analysis (PCA) showed that the majority of Cdwheat originated from Cd-2 (exchangeable), Cd-4 (humic acid-bound), and Cd-7 (residual). Furthermore, the results of the stepwise multiple linear regression (SMLR) showed that three fractions were primarily controlled by Cd-T: clay, cation exchange capacity (CeC), and total organic carbon (TOC). In addition, the total cancer risk (CR) of Cd in multiple media was, in the order wheat > water > soil > air. It is noteworthy that the Cd content in underground water and wheat by the ingestion pathway posed cancer risks to the local residents and provided a comprehensive insight into multiple media environment management. Furthermore, it provides a very significant basic study for detailed research into the mobility and transformation for factions.
Street dust is repeatedly raised by the wind as a secondary suspension, helping heavy metals therein to enter the human body through the respiratory system, harming human health. A detailed investigation was conducted to determine levels and sources of Cd (cadmium), Cr (chromium), Cu (copper), Pb (lead), Zn (zinc), Ni (nick), and Hg (mercury) contamination in street dust from Shijiazhuang, China. The average concentrations of these metals were: Cd, 1.86 mg·kg−1; Cr, 131.7 mg·kg−1; Ni, 40.99 mg·kg−1; Cu, 91.06 mg·kg−1; Pb, 154.78 mg·kg−1, Hg, 0.29 mg·kg−1; and Zn, 496.17 mg·kg−1—all of which were greater than the local soil reference values. The concentrations of the heavy metals were mapped for the three Shijiazhuang ring roads, with the results showing significant differences between each ring. Application of enrichment factors and geoaccumulation indexes showed that there was significant enrichment and accumulation of Cd, Pb, Zn, and Hg. Multivariate statistical analyses showed that Cd, Pb, Zn, and Hg levels were mainly controlled by human activities, while Cr, Ni, and Cu levels were associated with natural sources. Absolute principal component scores with multiple linear regression (APCS-MLR) were applied to facilitate source apportionment. The results showed that the mixed (traffic and industry) group contributed 53.55%, 59.7%, and 62.25% of the Cd, Pb, and Zn concentration, respectively, while the natural sources group contributed 58.01%, 65.09%, and 66.91% of the Cu, Ni, and Cr concentration, respectively. The burning coal group was found to be responsible for 63.38% of the Hg present in the samples. These results provide a useful theoretical basis for Shijiazhuang authorities to address heavy metal pollution management.
Samples of atmospheric depositions from five types of functional areas in Shijiazhuang, Hebei Province, China, were collected, and the concentrations of six toxic heavy metals (Cd, Cr, Cu, Pb, Ni, and Zn) were measured. Geographic information system, Pb isotope assessment, multivariate statistical analysis (principal component analysis, PCA), the geoaccumulation index (Igeo), potential ecological risk index (PERI), and a health risk assessment model were used to study the degree of pollution, identify sources of pollution, and assess the health risks to children and adults via three pathways (hand–mouth intake, skin contact, and respiration). The results show that the high traffic volume and exhaust gas emissions have led to high concentrations of heavy metals. The Igeo and PERI values of Cd (0.38–2.0 and 108–4531, respectively), indicating the present high pollution level and potential risk, respectively, varied the most. Pb isotope and PCA showed that Pb, Zn, and Cd from atmospheric deposition come from power plants and traffic—Cu is related to traffic, and Ni and Cr come mainly from soil particles (natural source). The health risk assessment showed that heavy metals in atmospheric depositions are at a safe level in the study area.
The healthy development of the city has received widespread attention in the world, and urban resilience is an important issue in the study of urban development. In order to better provide a useful reference for urban resilience and urban health development, this paper takes 56 cities in China as the research object, and selects 29 indicators from urban infrastructure, economy, ecology and society. The combination weight method, exploratory spatial data analysis (ESDA) and spatial measurement model are used to explore the spatial distribution of urban resilience and its influencing factors. From 2006 to 2017, the urban resilience of prefecture-level cities in the four provinces showed a wave-like rise. During the study period, the urban resilience values, measured as Moran’s Is, were greater than 0.3300, showing a significantly positive correlation in regard to their spatial distribution. Regarding the local spatial correlation, the urban resilience of the study area had spatial agglomeration characteristics within the province, with a significant distribution of "cold hot spots" in the spatial distribution. From the perspective of the factors that affected urban resilience, the proportion of the actual use of foreign capital in GDP and carbon emissions per 10,000 CNY of GDP had a negative impact and GDP per square kilometer, the proportion of urban pension insurance coverage, the proportion of the population with higher education, and expenditure to maintain and build cities had a positive impact. The development strategy of urban resilience must be combined with the actual situation of the region, and the rational resilience performance evaluation system and the top-level design of urban resilience improvement should be formulated to comprehensively improve urban resilience.
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