Membrane-based separations can improve energy efficiency and reduce the environmental impacts associated with traditional approaches. Nevertheless, many challenges must be overcome to design membranes that can replace conventional gas separation processes. Here, we report on the incorporation of engineered submicrometre-sized metal-organic framework (MOF) crystals into polymers to form hybrid materials that successfully translate the excellent molecular sieving properties of face-centred cubic (fcu)-MOFs into the resultant membranes. We demonstrate, simultaneously, exceptionally enhanced separation performance in hybrid membranes for two challenging and economically important applications: the removal of CO and HS from natural gas and the separation of butane isomers. Notably, the membrane molecular sieving properties demonstrate that the deliberately regulated and contracted MOF pore-aperture size can discriminate between molecular pairs. The improved performance results from precise control of the linkers delimiting the triangular window, which is the sole entrance to the fcu-MOF pore. This rational-design hybrid approach provides a general toolbox for enhancing the transport properties of advanced membranes bearing molecular sieve fillers with sub-nanometre-sized pore-apertures.

Novel ultrathin dual-functional metalenses are proposed, fabricated, tested, and verified in the microwave regime for the first time. The significance is that their anomalous transmission efficiency almost reaches the theoretical limit of 25%, showing a remarkable improvement compared with earlier ultrathin metasurface designs with less than 5% coupling efficiency. The planar metalens proposed empowers significant reduction in thickness, versatile focusing behavior, and high transmission efficiency simultaneously.

Geometric-phase metasurfaces, recently utilized for controlling wavefronts of circular polarized (CP) electromagnetic waves, are drastically limited to the cross-polarization modality. Combining geometric with propagation phase allows to further control the co-polarized output channel, nevertheless addressing only similar functionality on both co-polarized outputs for the two different CP incident beams. Here we introduce the concept of chirality-assisted phase as a degree of freedom, which could decouple the two co-polarized outputs, and thus be an alternative solution for designing arbitrary modulated-phase metasurfaces with distinct wavefront manipulation in all four CP output channels. Two metasurfaces are demonstrated with four arbitrary refraction wavefronts, and orbital angular momentum modes with four independent topological charge, showcasing complete and independent manipulation of all possible CP channels in transmission. This additional phase addressing mechanism will lead to new components, ranging from broadband achromatic devices to the multiplexing of wavefronts for application in reconfigurable-beam antenna and wireless communication systems.

Geometric metasurfaces primarily follow the physical mechanism of Pancharatnam–Berry (PB) phases, empowering wavefront control of cross‐polarized reflective/transmissive light components. However, inherently accompanying the cross‐polarized components, the copolarized output components have not been attempted in parallel in existing works. Here, a general method is proposed to construct phase‐modulated metasurfaces for implementing functionalities separately in co‐ and cross‐polarized output fields under circularly polarized (CP) incidence, which is impossible to achieve with solely a geometric phase. By introducing a propagation phase as an additional degree of freedom, the electromagnetic (EM) energy carried by co‐ and cross‐polarized transmitted fields can be fully phase‐modulated with independent wavefronts. Under one CP incidence, a metasurface for separate functionalities with controllable energy repartition is verified by simulations and proof‐of‐principle microwave experiments. A variety of applications can be readily expected in spin‐selective optics, spin‐Hall metasurfaces, and multitasked metasurfaces operating in both reflective and transmissive modes.

In this paper, ultra-thin metalenses are proposed to generate converging and non-diffractive vortex beam carrying orbital angular momentum (OAM) in microwave region. Phase changes are introduced to the transmission cross-polarized wave by tailoring spatial orientation of Pancharatnam-Berry phase unit cell. Based on the superposition of phase profile of spiral phase plate and that of a converging lens or an axicon, vortex beam carrying OAM mode generated by the metalens can also exhibit characteristics of a focusing beam or a Bessel beam. Measured field intensities and phase distributions at microwave frequencies verify the theoretical design procedure. The proposed method provides an efficient approach to control the radius of vortex beam carrying OAM mode in microwave wireless applications for medium-short range distance.

in Wiley Online Library (wileyonlinelibrary.com)ZIF-8/6FDA-DAM, a proven mixed-matrix material that demonstrated remarkably enhanced C 3 H 6 /C 3 H 8 selectivity in dense film geometry, was extended to scalable hollow fiber geometry in the current work. We successfully formed duallayer ZIF-8/6FDA-DAM mixed-matrix hollow fiber membranes with ZIF-8 nanoparticle loading up to 30 wt % using the conventional dry-jet/wet-quench fiber spinning technique. The mixed-matrix hollow fibers showed significantly enhanced C 3 H 6 /C 3 H 8 selectivity that was consistent with mixed-matrix dense films. Critical variables controlling successful formation of mixed-matrix hollow fiber membranes with desirable morphology and attractive transport properties were discussed. Furthermore, the effects of coating materials on selectivity recovery of partially defective fibers were investigated. To our best knowledge, this is the first article reporting successful formation of high-loading mixed-matrix hollow fiber membranes with significantly enhanced selectivity for separation of condensable olefin/paraffin mixtures. Therefore, it represents a major step in the research area of advanced mixed-matrix membranes. Published on behalf of the AIChE Spinning parameters of the spinning state showing the highest fiber selectivity are shown in parentheses.

Regarding miniaturized and integrated systems, a single flat device that possesses diversified functionalities is highly desirable in optical to microwave regimes. With this perspective, bifunctional metalenses constructed by meta-atoms with integrated response to propagation phase and geometric phase are proposed for independent manipulation of right-handed and left-handed circularly polarized waves. The derived general criterion is verified in the microwave region from three bifunctional metalenses operating in transmission manner. The proof-of-concept measurements show that all these metalenses exhibit two independent functionalities that can be switched by flipping the helicity of the incident illumination. Very high efficiencies of around 80%, with peak value of 91%, are achieved by the ultrathin metasurfaces of thickness 0.15λ0. The proposed metasurfaces provide a promising route for the realization of reconfigurable lenses and antennas in wireless communication systems.

Vortex beam carrying orbital angular momentum (OAM) has been widely explored in optical and microwave regions attributed to its potential characteristics in communication systems. For circular polarization incidence, Pancharatnam–Berry (PB) phase is a direct resource to generate phase gradient along the azimuthal direction required by specific OAM mode. The main drawback of PB phase is that it only affects cross‐polarized fields and keeps the copolarized part unmodulated. Here, a paradigm‐shift perspective of noninterleaved metasurfaces is proposed, which can simultaneously generate separate multiple integer and fractional OAM modes occupying both copolarized and cross‐polarized output channels. The scheme is validated by a series of experimental demonstrations in the microwave regime. By adjusting the polarization states of both input and receiving ends, different integer and fractional OAM modes are demonstrated in the full transmission channels. The results offer a unique recipe to enhance information capacity of metasurfaces and trigger versatile electromagnetic (EM) wave function integrations for advanced compact systems. A variety of applications can be readily expected in spin‐selective optics, spin‐Hall metadevices, and multitask metasurfaces operating in both reflection and transmission modes.