Poly(p-dioxanone) (PPDO) is widely recognized to be a bioabsorbable material for biomedical applications, and its crystalline morphology is dependent on the crystallization temperature and polymorphism. The PPDO ringless spherulite (RLS, at T c = 30–40 °C) has a mixture of α′- and α-crystals, while the α-crystal is predominant in the ring-banded spherulite (RBS) (T c = 60–78 °C). The interior structure of PPDO-RBS is characterized by microbeam X-ray and interior-dissected morphology analysis. The double ring-banded RBS consists of horizontal lamellae beneath valleys and vertical lamellae in the ridges. Optimal band spacing and the ridge-valley height difference produce photonic iridescence colors in PPDO-RBS at 60–70 °C. Additionally, ring-band growth patterns can be customized from 2.9 to 10.9 μm by tuning the temperature program. Thus, custom-tailoring the crystal growth produces multiple and versatile combinations of ring-banded patterns in a wide range of orders for inducing the photonic reflection behavior.
Amorphous poly(p-vinyl phenol) (PVPh) was added into semicrystalline poly(p-dioxanone) (PPDO) to induce a uniquely novel dendritic/ringed morphology. Polarized-light optical, atomic-force and scanning electron microscopy (POM, AFM, and SEM) techniques were used to observe the crystal arrangement of a uniquely peculiar cactus-like dendritic PPDO spherulite, with periodic ring bands not continuingly circular such as those conventional types reported in the literature, but discrete and detached to self-assemble on each of the branches of the lobs. Correlations and responsible mechanisms for the formation of this peculiar banded-dendritic structure were analyzed. The periodic bands on the top surface and interior of each of the cactus-like lobs were discussed. The banded pattern was composed of feather-like lamellae in random fractals alternately varying their orientations from the radial direction to the tangential one. The tail ends of lamellae at the growth front spawned nucleation cites for new branches; in cycles, the feather-like lamellae self-divided into multiple branches following the Fibonacci sequence to fill the ever-expanding space with the increase of the radius. The branching fractals in the sequence and the periodic ring-banded assembly on each of the segregated lobs of cactus-like dendrites were the key characteristics leading to the formation of this unique dendritic/ringed PPDO spherulite.
The exterior and interior lamellar assemblies of poly(p-dioxanone) (PPDO) crystallized at 76 °C yield the most regular ones to interpret the 3D assembly mechanisms and potential for structural coloration iridescence, which are investigated using atomic-force microscopy (AFM), and scanning electron microscopy (SEM). PPDO displays two types of ring-banded spherulites within a range of Tc with dual-type birefringent spherulites (positive and negative-type) only within a narrow range of Tcs = 70–78 °C. At Tc > 80 °C, the inter-band spacing decreases from a maximum and the crystal assembly becomes irregularly corrupted and loses the capacity for light interference. Periodic grating assemblies are probed by in-depth 3D dissection into periodically banded crystal aggregates of poly(p-dioxanone) (PPDO) to disclose such layered gratings possessing iridescence features similar to nature’s structural coloration. This work amply demonstrates that grating assembly by orderly stacked crystal layers is feasible not only for accounting for the periodic birefringent ring bands with polarized light but also the distinct iridescence by interfering with white light.
Multiple frequency global navigation satellite system (GNSS) has become more complex due to the existence of extra channels. Typically, auxiliary methods are used to synchronize the second signals at other bands by aiding the acquired channel parameters. However, there are critical limitations because the reception of GNSS signals is subject to uncertainties due to noise carrier injection or circuit interference. The relationship between the two Doppler frequencies can be affected by uncertainties. Therefore, we aimed to implement an efficient dual-frequency field-programmable gate array (FPGA), performing a direct aid tracking method for the secondary channel to achieve resource efficiency and inner aid robustness. A robust estimator that directly links two loops in the two bands is proposed. In this scheme, (1) a robust estimator able to cope with uncertainty; (2) a primary tracking scheme to obtain the error boundary, and (3) a tracked bit-boundary for the initial code phase of the second channel are used. Based on experiments on the FPGA, the robust channel link can achieve direct aid tracking, and 31.02% of the original hardware resources from the aided acquisition module were released satisfactorily.
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