Enantiopure (S,S) and (R,R) dimethyl-ethylenedithio-tetrathiafulvalene (DM-EDT-TTF) 1 donors are synthesized by cross coupling followed by decarboxylation reactions. In the solid state the methyl groups are arranged in axial positions within sofa-type conformation for the six-membered rings. Crystalline radical cation salts formulated as [(S,S)-1]2PF6, [(R,R)-1]2PF6, and [(rac)-1]2PF6 are obtained by electrocrystallization. When the experiment is conducted with enantioenriched mixtures both enantiopure and racemic phases are obtained. The monoclinic enantiopure salts, containing four independent donors in the unit cell, show semiconducting behavior supported by band structure calculations of extended Hückel type. The racemic salt contains only one independent donor in the mixed valence oxidation state +0.5. Under ambient pressure the racemic material is metallic down to 120 K, while an applied pressure of 11.5 kbar completely suppresses the metal-insulator transition. Band structure calculations yield an open Fermi surface, typical for a pseudo-one-dimensional metal, with unperfected nesting, thus ruling out the possibility of charge or spin density modulations to be at the origin of the transition. Raman spectroscopy measurements, in agreement with structural analysis at 100 K, show no indication of low-temperature charge ordering in the racemic material at ambient pressure, thus suggesting Mott-type charge localization for the observed metal-insulator transition.

We show that the entropy production in small open systems coupled to environments made of extended baths is predominantly caused by the displacement of the environment from equilibrium rather than, as often assumed, the mutual information between the system and the environment. The latter contribution is strongly bounded from above by the Araki-Lieb inequality, and therefore is not time-extensive, in contrast to the entropy production itself. We confirm our results with exact numerical calculations of the system-environment dynamics.whereĤ S (t),Ĥ E ,V (t) are the Hamiltonians of the system, environment and the interaction between the system arXiv:1905.03804v3 [cond-mat.stat-mech]

The study shows that presence of the quantum coherent, unitary component of the evolution of the system can improve constancy of heat engines, i.e., decrease fluctuations of the output power, in comparison with purely stochastic setups. This enables to overcome the recently derived tradeoff between efficiency, power and constancy, which applies to classical Markovian steady-state heat engines. The concept is demonstrated using a model system consisting of two tunnel-coupled orbitals (i.e., electronic levels), each attached to a separate electronic reservoir; such a setup can be realized, for example, using quantum dots. Electronic transport is studied by means of the exact Levitov-Lesovik formula in the case without the Coulomb interaction between electrons, as well as applying a quantum master equation in the interacting case. Constancy of the analyzed thermoelectric generator is increased due to the fact that tunneling between the orbitals is associated with a unitary evolution of the electron state instead of a stochastic Poisson transition. This reduces stochasticity of the system, thus suppressing the current and power fluctuations. Moreover, noise can be further reduced by the Coulomb interaction between electrons which prevents the double occupancy of the system.