Security of supply of a number of raw materials is of concern for the European Union; foremost among these are the rare earth elements (REE), which are used in a range of modern technologies. A number of research projects, including the EURARE and ASTER projects, have been funded in Europe to investigate various steps along the REE supply chain. This paper addresses the initial part of that supply chain, namely the potential geological resources of the REE in Europe. Although the REE are not currently mined in Europe, potential resources are known to be widespread, and many are being explored. The most important European resources are associated with alkaline igneous rocks and carbonatites, although REE deposits are also known from a range of other settings. Within Europe, a number of REE metallogenetic belts can be identified on the basis of age, tectonic setting, lithological association and known REE enrichments. This paper reviews those metallogenetic belts and sets them in their geodynamic context. The most well-known of the REE belts are of Precambrian to Palaeozoic age and occur in Greenland and the Fennoscandian Shield. Of particular importance for their REE potential are the Gardar Province of SW Greenland, the Svecofennian Belt and subsequent Mesoproterozoic rifts in Sweden, and the carbonatites of the Central Iapetus Magmatic Province. However, several zones with significant potential for REE deposits are also identified in central, southern and eastern Europe, including examples in the Bohemian Massif, the Iberian Massif, and the Carpathians.
High-precision 60Fe-60Ni isotope data show that most meteorites originating from differentiated planetesimals that accreted within 1 million years of the solar system's formation have 60Ni/58Ni ratios that are approximately 25 parts per million lower than samples from Earth, Mars, and chondrite parent bodies. This difference indicates that the oldest solar system planetesimals formed in the absence of 60Fe. Evidence for live 60Fe in younger objects suggests that 60Fe was injected into the protoplanetary disk approximately 1 million years after solar system formation, when 26Al was already homogeneously distributed. Decoupling the first appearance of 26Al and 60Fe constrains the environment where the Sun's formation could have taken place, indicating that it occurred in a dense stellar cluster in association with numerous massive stars.
Detrital zircons from high-grade metasedimentary rocks (Krummedal supracrustal sequence) in the East Greenland Caledonian orogen yield ion-microprobe U–Pb ages mainly in the range 1100–1800 Ma but with a few grains of
c
. 1000 Ma, different from zircon ages (mainly 1800–2800 Ma) obtained from the crystalline basement that underlies the metasedimentary rocks. These results indicate that original deposition of the Krummedal sequence took place after 1000–1100 Ma ago, and that the sediment was not derived from the underlying crystalline basement, but from younger, at present unknown sources. High-grade metamorphism of the Krummedal sequence and formation of anatectic granites took place around 930 Ma ago. Caledonian granites are also present in the region, but cannot be distinguished on visual criteria in the field from the older granites, unless emplaced into a younger (900–600 Ma) sequence of sedimentary rocks, the Eleonore Bay Supergroup. It is not yet certain whether the high-grade metamorphism and granite formation at
c
. 930 Ma are related to a ‘Grenvillian’ or slightly younger collisional event, or to an episode of rifting and crustal thinning. If present at all, a ‘Grenvillian’ orogen in East Greenland would be of very different character than that in North America and southern Scandinavia.
Detrital zircon data from the upper parts of the Proterozoic Hess Canyon Group of southern Arizona reveal abundant 1600-1488 Ma detrital zircons, which represent ages essentially unknown from southern Laurentia. This basinal succession concordantly overlies a >2-km-thicksection of 1657 ± 3 Ma rhyolite of the Redmond Formation. The rhyolite is intercalated with and hence contemporaneous with the lower parts of the overlying White Ledges Formation, a 300-m-thick orthoquartzite unit at the base of the Hess Canyon Group. These quartzites contain a unimodal detrital zircon age probability distribution with peak ages of 1778, 1767, and 1726 Ma, supporting regional correlation with other ca. 1.65 Ga quartzite exposures in southwestern Laurentia. However, the ~900-m-thick argillaceous Yankee Joe and minimum 600-m-thick quartzite-rich Blackjack Formations contain younger detrital zircons, with peak ages ranging from 1666 to 1494 Ma and a maximum depositional age of 1488 ± 9 Ma. Prominent age peaks at 1582-1515 Ma and 1499-1488 Ma represent detritus that is exotic and not derived from known southern Laurentian sources. The Blackjack Formation is cut by the 1436 ± 2 Ma Ruin Granite, indicating that deposition, deformation, and intrusion occurred between 1488 and 1436 Ma. This basin likely developed before or in the early stages of the 1.45-1.35 Ga intracontinental tectonism in southwestern Laurentia. Our fi ndings necessitate the presence of an ~170 m.y. disconformity within the Hess Canyon Group and document a previously unrecognized episode of Mesoproterozoic basin sedimentation (>1.5 km of section) between 1488 and 1436 Ma in southern Laurentia. This new record helps to fi ll the 1.60-1.45 Ga magmatic gap in southern Laurentia and supports hypotheses for a long-lived Proterozoic tectonic margin along southern Laurentia from 1.8 to 1.0 Ga. The 1.6-1.5 Ga detrital zircon ages offer important new constraints for ca. 1.5 Ga Nuna reconstructions and for the paleogeography of contemporaneous basins such as the Belt Basin in western Laurentia.
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