There is growing interest in geochronological applications of terrestrial in situ-produced cosmogenic nuclides, with the most commonly measured being 10 Be and 26 Al in quartz. To extract and then separate these radionuclides from quartz and prepare them in the oxide form suitable for accelerator mass spectrometry (AMS) requires extensive and careful laboratory processing. Here we discuss the suitability of a crushed, sieved and etched, sub-aerially exposed vein quartz specimen (CoQtz-N) to act as a reference material for chemical laboratory preparation and AMS measurements. Splits of CoQtz-N were distributed to eleven target preparation laboratories. The CoQtz-N 10 Be targets were then measured at seven different AMS facilities and five of the preparation laboratories had their 26 Al targets measured at four different AMS facilities. We show that CoQtz-N splits are sufficiently homogeneous with regard to nuclide concentrations, that it has been cleaned of any atmospheric derived (i.e. meteoric) 10 Be and that it has low concentrations of the major elements that can interfere with Be and Al extraction chemistry and AMS measurements. We derive preliminary concentrations for 10 Be and 26 Al in CoQtz-N as 2.53 ±

Catchment-wide denudation rates (CWDRs) obtained from cosmogenic nuclides are an effi cient way to determine geomorphic processes quantitatively in alpine mountain ranges over Holocene time scales. These rate estimations assume steady geomorphic processes. Here we use a time series (3 yr) in the Aare catchment (central Swiss Alps) to test the impact of spatially heterogeneous stochastic sediment supply on CWDRs. Our results show that low-frequency, high-magnitude debris-fl ow events signifi cantly perturb cosmogenic nuclide ( 10 Be, 14 C) concentrations and thus CWDRs. The 10 Be concentrations decrease by a factor of two following debris-fl ow events, resulting in a doubling of inferred CWDRs. The variability indicates a clear time and source dependency on sediment supply, with restricted area-weighted mixing of sediment. Accordingly, in transient environments, it is critical to have an understanding of the history of geomorphic processes to derive meaningful CWDRs. We hypothesize that the size of debris fl ows, their connectivity with the trunk stream, and the ability of the system to suffi ciently mix sediment from low-and highorder catchments control the magnitude of CWDR perturbations. We also determined in situ 14 C in a few samples. In conjunction with 10 Be, these data suggest partial storage for colluvium of a few thousand years within the catchment prior to debris-fl ow initiation.

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