The present study systematically investigates the effect of heat treatment atmosphere on the multistage R-phase transformation (MRT) in an aged Ti-51.0 at%Ni alloy. No MRT occurs when the heat treatments were completed under the regulated atmosphere. On the other hand, the MRT is observed in the specimen heat treated under the unregulated atmosphere. It is apparent from transmission electron microscope observations that the first and the second transformations take place around the grain boundary and at the grain interior, respectively. We conclude that the MRT is extrinsic, and is an artifact during the heat treatment, rather than intrinsic in nature.
It has been demonstrated with systematic experiments that the appearance and disappearance of multistage martensitic transformation (MMT) in aged Ni-rich Ti-Ni alloys depend on the heat treatment conditions. No multistage transformation occurs when the evaporation of Ti and Ni and/or the preferential oxidation of Ti in the specimen are prevented and the purification of heat treatment atmosphere in an evacuated quartz tube is achieved. The heterogeneity in precipitation morphology of the Ti 3 Ni 4 phase, which is responsible for the multistage transformation can be suppressed with the regulation of heat treatment atmosphere as mentioned above. We have concluded that the multistage martensitic transformation in aged Ni-rich Ti-Ni alloys is extrinsic in nature, and is an artifact during the heat treatment.
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