Aging of a power transformer's insulation system produces carboxylic acids. These acids-acetic, formic and levulinic-are absorbed by the paper insulating material, thus accelerating the degradation of the whole insulation system. In this contribution, the effect of these acids on the aging of oil-impregnated paper insulation used in power transformer is reported. A laboratory aging experiment considering different concentrations of these three acids was performed to assess their effect on the insulation system's degradation. Each acid was individually mixed with virgin oil, and a mixture of acids was also blended with oil. The paper's degradation was assessed by the degree of polymerization (DPv). It was found that the DPv of paper aged with formic acid decreased much faster in comparison to the other acids.
Among the main causes of outdoor insulation failures is their poor specifications in terms of leakage distances. This happens when the selected criteria are unable to cope with all the stresses imposed by the changes in environmental pollutions. Therefore, it is important for utilities to fully understand the actual pollution characteristics of the service environment in which the insulators are operating. In this paper, the pollution severity and performance of some 13.2 kV ceramic insulators, sampled in different areas of a Canadian aluminum factory, are assessed. The investigations were performed taking into account the influence of air humidity. Various characteristics were investigated to assess the pollution levels of the insulators, such as equivalent salt deposit density (ESDD) and non-soluble deposit density (NSDD), surface resistance, and leakage current characteristics (density, 3rd harmonic amplitude, and phase). It was witnessed that the insulators, collected around the factory, were much more polluted in comparison to the initial expectation. The pollution level should not be considered static due to the environmental parameters’ dynamics. Lessons to learn: the reliability of an electrical grid is dependent on components whose own reliability is strongly affected by external factors, of which there is often a poor awareness. If care is not taken to re-evaluate the post-installation pollution levels of the insulators, the light may simply turn out!
Esters based dielectric fluids have been widely researched since 1990's for application in high voltage insulation applications. Since then, researchers are affirmative towards usage of ester based insulating fluids as a replicated to mineral insulation oils. The operating properties and aging performance of ester oils proved to be potential candidates for high voltage applications. In view of high temperatures and longevity of insulation systems, there also is a need to understand the chemical perspectives along with aging behaviour of ester oils. Accelerated aging of oil/paper insulation associated with mineral oil and synthetic ester with cellulose insulant has been experimentally simulated as per ASTM D 1934 at 115°C. Fourier Transform Infrared spectroscopy analysis of oils and cellulose papers is carried out at different aging factors. The compositional changes in oils and cellulose kraft paper with aging have been enumerated. The changes in the absorbance area for appropriate functional groups have been also reported. It is found that, the chemical stability of synthetic esters is superior to that of the mineral oil.
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