The magnetovolume effect has been investigated using a supersaturated solid solution of a Co–19 at. %Cu alloy processed by electrodeposition. The enhanced saturation magnetization of the Co–Cu alloy was attributed to both metastable fcc Co and lattice expansion. The density functional theory using the CASTEP code revealed that an enhanced magnetic moment due to the magnetovolume effect is obtained in fcc Co, but not in hcp Co.
Three kinds of nanocrystalline Co-Cu alloys: a nanocrystalline Co-Cu alloy with nanoscale lamellar structure, a supersaturated solid solution Co-Cu alloy and a nanocrystalline two-phase Co-Cu alloy were processed by electrodeposition, and their mechanical properties were investigated at room temperature. These nanocrystalline Co-Cu alloys showed the high hardness and the low activation volume. The mechanical properties of the nanocrystalline Co-Cu alloys strongly depended on the grain boundary characteristics. Molecular dynamics simulations were performed in the two-phase nanocrystalline Co-Cu alloy to investigate the dislocation emission at the Co/Cu interface. The MD simulations showed that the stacking faults, which are generated by the intense geometrical strain at the Co/Cu interface, play an important role in the dislocation emission.
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