The performance of magnetic nanoparticles is intimately entwined with their structure, mean size and magnetic anisotropy. Besides, ensembles offer a unique way of engineering the magnetic response by modifying the strength of the dipolar interactions between particles. Here we report on an experimental and theoretical analysis of magnetic hyperthermia, a rapidly developing technique in medical research and oncology. Experimentally, we demonstrate that single-domain cubic iron oxide particles resembling bacterial magnetosomes have superior magnetic heating efficiency compared to spherical particles of similar sizes. Monte Carlo simulations at the atomic level corroborate the larger anisotropy of the cubic particles in comparison with the spherical ones, thus evidencing the beneficial role of surface anisotropy in the improved heating power. Moreover we establish a quantitative link between the particle assembling, the interactions and the heating properties. This knowledge opens new perspectives for improved hyperthermia, an alternative to conventional cancer therapies.
The superheating of a solid to a temperature beyond its melting point, without the solid actually melting, is a well-known phenomenon. It occurs with many substances, particularly those that can readily be produced as high-quality crystals. In principle, ice should also be amenable to superheating. But the complex three-dimensional network of hydrogen bonds that holds water molecules together and gives rise to unusual solid and liquid properties strongly affects the melting behaviour of ice; in particular, ice usually contains many defects owing to the directionality of its hydrogen bonds. However, simulations are readily able to 'create' defect-free ice that can be superheated. Here we show that by exciting the OH stretching mode of water, it is possible to superheat ice. When using an ice sample at an initial temperature of 270 K, we observe an average temperature rise of 20 +/- 2 K that persists over the monitored time interval of 250 ps without melting.
Using a reaction microscope, three-dimensional (3D) electron (and ion) momentum (P) spectra have been recorded for carrier-envelope-phase (CEP) stabilized few-cycle ( approximately 5 fs), intense ( approximately 4 x 10(14) W/cm2) laser pulses (740 nm) impinging on He. Preferential emission of low-energy electrons (E(e)<15 eV) to either hemisphere is observed as a function of the CEP. Clear interference patterns emerge in P space at CEPs with maximum asymmetry, interpreted as attosecond interferences of rescattered and directly emitted electron wave packets by means of a simple model.
We report photoelectron energy spectra, momentum, and angular distributions for the strong-field single ionization of lithium by 30 femtosecond laser pulses. For peak intensities between 10 11 and 10 14 W/cm 2 at a central wavelength of 785 nm, the classical over-the-barrier intensity was reached well inside the multiphoton regime. The complete vector momenta of the ionization fragments were recorded by a reaction microscope with a magneto-optically trapped target (MOTREMI). On the theoretical side, the time-dependent Schrödinger equation was solved by two independent methods seeking the solution directly on a radial grid. Distinct differences between the results of both calculations and also in comparison with experiment point to a high sensitivity of this reaction with respect to small details, particularly in the description of the Li+ core.
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