Soil properties estimation with the use of reflectance spectroscopy has met major advances over the last decades. Their non-destructive nature and their high accuracy capacity enabled a breakthrough in the efficiency of performing soil analysis against conventional laboratory techniques. As the need for rapid, low cost, and accurate soil properties’ estimations increases, micro electro mechanical systems (MEMS) have been introduced and are becoming applicable for informed decision making in various domains. This work presents the assessment of a MEMS sensor (1750–2150 nm) in estimating clay and soil organic carbon (SOC) contents. The sensor was first tested under various experimental setups (different working distances and light intensities) through its similarity assessment (Spectral Angle Mapper) to the measurements of a spectroradiometer of the full 350–2500 nm range that was used as reference. MEMS performance was evaluated over spectra measured from 102 samples in laboratory conditions. Models’ calibrations were performed using random forest (RF) and partial least squares regression (PLSR). The results provide insights that MEMS could be employed for soil properties estimation, since the RF model demonstrated solid performance over both clay (R2 = 0.85) and SOC (R2 = 0.80). These findings pave the way for supporting daily agriculture applications and land related policies through the exploration of a wider set of soil properties.

Remote sensing and soil spectroscopy applications are valuable techniques for soil property estimation. Soil organic matter (SOM) and calcium carbonate are important factors in soil quality, and although organic matter is well studied, calcium carbonates require more investigation. In this study, we validated the performance of laboratory soil spectroscopy for estimating the aforementioned properties with referenced in situ data. We also examined the performance of imaging spectroscopy sensors, such as the airborne HySpex and the spaceborne PRISMA. For this purpose, we applied four commonly used machine learning algorithms and six preprocessing methods for the evaluation of the best fitting algorithm.. The study took place over crop areas of Amyntaio in Northern Greece, where extensive soil sampling was conducted. This is an area with a very variable mineralogical environment (from lignite mine to mountainous area). The SOM results were very good at the laboratory scale and for both remote sensing sensors with R2 = 0.79 for HySpex and R2 = 0.76 for PRISMA. Regarding the calcium carbonate estimations, the remote sensing accuracy was R2 = 0.82 for HySpex and R2 = 0.36 for PRISMA. PRISMA was still in the commissioning phase at the time of the study, and therefore, the acquired image did not cover the whole study area. Accuracies for calcium carbonates may be lower due to the smaller sample size used for the modeling procedure. The results show the potential for using quantitative predictions of SOM and the carbonate content based on soil and imaging spectroscopy at the air and spaceborne scales and for future applications using larger datasets.

In-situ infrared soil spectroscopy is prone to the effects of ambient factors, such as moisture, shadows, or roughness, resulting in measurements of compromised quality, which is amplified when multiple sensors are used for data collection. Aiming to provide accurate estimations of common physicochemical soil properties, such as soil organic carbon (SOC), texture, pH, and calcium carbonates based on in-situ reflectance captured by a set of low-cost spectrometers operating at the shortwave infrared region, we developed an AI-based spectral transfer function that maps fields to laboratory spectra. Three test sites in Cyprus, Lithuania, and Greece were used to evaluate the proposed methodology, while the dataset was harmonized and augmented by GEO-Cradle regional soil spectral library (SSL). The developed dataset was used to calibrate and validate machine learning models, with the attained predictive performance shown to be promising for directly estimating soil properties in-situ, even with sensors with reduced spectral range. Aiming to set a baseline scenario, we completed the exact same modeling experiment under laboratory conditions and performed a one-to-one comparison between field and laboratory modelling accuracy metrics. SOC and pH presented an R2 of 0.43 and 0.32 when modeling the in-situ data compared to 0.63 and 0.41 of the laboratory case, respectively, while clay demonstrated the highest accuracy with an R2 value of 0.87 in-situ and 0.90 in the laboratory. Calcium carbonates were also attempted to be modeled at the studied spectral region, with the expected accuracy loss from the laboratory to the in-situ to be observable (R2 = 0.89 for the laboratory and 0.67 for the in-situ) but the reduced dataset variability combined with the calcium carbonate characteristics that are spectrally active in the region outside the spectral range of the used in-situ sensor, induced low RPIQ values (less than 0.50), signifying the importance of the suitable sensor selection.

Spectroscopy is a widely used technique that can contribute to food quality assessment in a simple and inexpensive way. Especially in grape production, the visible and near infrared (VNIR) and the short-wave infrared (SWIR) regions are of great interest, and they may be utilized for both fruit monitoring and quality control at all stages of maturity. The aim of this work was the quantitative estimation of the wine grape ripeness, for four different grape varieties, by using a highly accurate contact probe spectrometer that covers the entire VNIR–SWIR spectrum (350–2500 nm). The four varieties under examination were Chardonnay, Malagouzia, Sauvignon-Blanc, and Syrah and all the samples were collected over the 2020 and 2021 harvest and pre-harvest phenological stages (corresponding to stages 81 through 89 of the BBCH scale) from the vineyard of Ktima Gerovassiliou located in Northern Greece. All measurements were performed in situ and a refractometer was used to measure the total soluble solids content (°Brix) of the grapes, providing the ground truth data. After the development of the grape spectra library, four different machine learning algorithms, namely Partial Least Squares regression (PLS), Random Forest regression, Support Vector Regression (SVR), and Convolutional Neural Networks (CNN), coupled with several pre-treatment methods were applied for the prediction of the °Brix content from the VNIR–SWIR hyperspectral data. The performance of the different models was evaluated using a cross-validation strategy with three metrics, namely the coefficient of the determination (R2), the root mean square error (RMSE), and the ratio of performance to interquartile distance (RPIQ). High accuracy was achieved for Malagouzia, Sauvignon-Blanc, and Syrah from the best models developed using the CNN learning algorithm (R2>0.8, RPIQ≥4), while a good fit was attained for the Chardonnay variety from SVR (R2=0.63, RMSE=2.10, RPIQ=2.24), proving that by using a portable spectrometer the in situ estimation of the wine grape maturity could be provided. The proposed methodology could be a valuable tool for wine producers making real-time decisions on harvest time and with a non-destructive way.

<p>Measuring soil reflectance in the field, rather than in a laboratory setting, can be very useful when it comes to numerous applications such as mapping the distribution of various soil properties, especially when prompt estimations are needed.  Recent advances in spectroscopy, and specifically in the development of low-cost Micro-Electro-Mechanical-Systems (MEMS) based spectrometers, pave the way for developing real-time applications in agriculture and environmental monitoring. Compared to high-end spectrometers, whose spectral range extends from Visible (VIS) and Near-InfraRed (NIR) to Shortwave InfraRed (SWIR), MEMS cover limited parts of the electromagnetic spectrum resulting in missing important information. In parallel, new space missions such as Planet Fusion are operationally ready and provide optical imagery (RGB and NIR) with high spatial (3m) and temporal (daily) resolution. To this end, we assessed the potential of augmenting the bands captured from a commercial MEMS sensor (Spectral Engines Nirone S2.2 @ 1750 – 2150 nm) by adjoining the Planet Fusion bands at the exact sampling date and location that in-situ scans originate.</p><p>Employing the above, a set of portable MEMS was used at a pilot area in Cyprus (Agia Varvara, Nicosia district) to develop a regional in-situ Soil Spectral Library (SSL). A set of 60 distinct locations were selected for capturing in situ spectral reflectance after the stratification of Planet Fusion pixels of the pilot area, while a physical soil sample was analyzed at the laboratory for the determination of Soil Organic Carbon (SOC) content. During the visit, topsoil moisture was also measured.</p><p>The resulting SSL, containing the in-situ spectra, SOC, and moisture content was further augmented by the 4 bands of Planet Fusion imagery acquired on the exact date of the field visit. At this stage, three Random Forest models for SOC content estimation were fitted using as explanatory variables initially only the MEMS data with moisture content, then Planet Fusion bands, and finally all three available inputs.</p><p>The results presented an observable decrease in RMSE of SOC content estimations when fusing in-situ with spaceborne data, highlighting the importance of the information contained at VIS-NIR when modeling SOC. On the other hand, the synergy of the two sensors is mutually beneficial; SOC absorption bands can also be found in the SWIR region and are hard to detect with remote sensing means since they fall within the strong water absorption region (around 1950 nm). MEMS-based systems operating at the SWIR part can support this process, and if combined with ancillary environmental measurements such as soil moisture, can provide a cost-effective solution for measuring SOC and other soil-related parameters. To loosen the necessity of laboratory analysis, it is necessary to establish protocols and guidelines for spectral data collection and management to ensure that the data collected is consistent and of high quality and develop representative SSLs that can be used to serve different modeling scenarios. </p>

A sustainable process for valorization of onion waste would need to entail preliminary sorting out of exhausted or suboptimal material as part of decision-making. In the present study, an approach for monitoring red onion skin (OS) phenolic composition was investigated through Visible Near-Short-Wave infrared (VNIR-SWIR) (350–2500 nm) and Fourier-Transform-Mid-Infrared (FT-MIR) (4000–600 cm−1) spectral analyses and Machine-Learning (ML) methods. Our stepwise approach consisted of: (i) chemical analyses to obtain reference values for Total Phenolic Content (TPC) and Total Monomeric Anthocyanin Content (TAC); (ii) spectroscopic analysis and creation of OS spectral libraries; (iii) generation of calibration and validation datasets; (iv) spectral exploratory analysis and regression modeling via several ML algorithms; and (v) model performance evaluation. Among all, the k-nearest neighbors model from 1st derivative VNIR-SWIR spectra at 350–2500 nm resulted promising for the prediction of TAC (R2 = 0.82, RMSE = 0.52 and RPIQ = 3.56). The 2nd derivative FT-MIR spectral fingerprint among 600–900 and 1500–1600 cm−1 proved more informative about the inherent phenolic composition of OS. Overall, the diagnostic value and predictive accuracy of our spectral data support the perspective of employing non-destructive spectroscopic tools in real-time quality control of onion waste.

The importance of monitoring soil properties is constantly increasing among researchers and policy-makers. In this context, it is imperative to identify cost effective and reliable strategies for soil mapping compared to the costlier traditional solutions. A wide range of tools are becoming available that enable better utilization of Earth Observation capabilities to monitor the soil ecosystem. This work is an effort of assessing the potential of Sentinel-2 imagery data for mapping Soil Organic Matter (SOM) contents and investigating the possibilities of its enhancement through ASTER derived information.The rural area around the lake Zazari, located in the Western Macedonia district of Greece, was chosen as study area. Initially, pixel-wise vegetation indices (NDVI and NBR2) were calculated, utilizing a local version of the CEOS Open Data Cube for masking Sentinel-2 bare soil pixels extending a three-year period (2017)(2018)(2019). The generated mask was used to extract soil spectral signatures at the image level over selected 100 field samples. The resulting time series was expanded through the conjunction of ASTER Thermal InfraRed bands by matching the exact data acquisition dates of two platforms.The conclusive part of the work contains the application of regression modelling to effectively assess soil variables. The local Partial Least Square regression algorithm was chosen, due to its characteristics of performing inherently local predictions. Five-fold cross-validation technique was used for reporting the models' accuracy, which was assessed through R 2 coefficient, RPIQ ratio and RMSE. The model estimated SOM values among a synthetic bare soil composite image that was acquired over study area's agricultural fields. Two models were trained and compared; one over Sentinel-2 imagery bands that were used as the predictor variables' set and a second over an expanded predictor variables' set, including ASTER thermal bands. The results signified evidence of accuracy increase of SOM content assessment, through spaceborne imagery analysis.