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Four new hydrothermal vent fields were discovered on the slow spreading Central Indian Ridge (8–12°S; Segments 1–3), all located off‐axis on abyssal hill structures or Ocean Core Complexes (OCCs). Each site was characterized using seafloor observation (towed camera system), plume chemistry (Fe, Mn, and CH4; Conductivity, Temperature, and Depth sensor [CTD]/Miniature Autonomous Plume Recorder [MAPR]), and rock sampling (TVgrab/dredges). Different styles of venting on each segment reflect different geological settings, rock types, likely heat sources, and fluid pathways. The segment 1 field was located on the western flank of the axial valley at the base of OCC‐1‐1. High‐temperature venting was inferred from plume characteristics and extensive seafloor sulfide mineralization, but only diffuse venting was observed. This site appears to be a magmatic‐influenced basaltic‐hosted system despite its off‐axis location. Two low‐temperature diffusely venting sites were located on abyssal hills 6 and 9 km off‐axis on Segment 2. Plume particle, metal, and CH4 concentrations were all very low, suggesting dilution of hydrothermal fluids by intrusion of seawater into the highly permeable flank area fault zone. The “Onnuri Vent Field” (OVF), located at the summit of OCC‐3‐2, vented clear, low‐temperature fluids supporting abundant vent organisms (21 macrofaunal taxa). The plume particle signal was low to absent, but strong ORP anomalies correlated with high CH4 and low metal concentrations. Sulfide mineralization was present, which suggests both serpentinization and magmatic/lithospheric influence on fluid composition. The detachment fault is the likely pathway for hydrothermal fluid circulation at this off‐axis location. These new vent field discoveries, especially the OVF, contribute valuable information toward understanding Indian Ocean hydrothermal systems and their ecology/biogeography.

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Copper, Zn and Pb isotope ratios are important tracers for understanding geological and biological processes. We present optimised column separation methods using an anion exchange resin for Cu and Zn, and a Pb-specific resin for Pb, and provide Cu, Zn and Pb isotope data for thirty-three commercially available geological and biological reference materials (RMs) using MC-ICP-MS. Our measurement procedures can be applied to various environmental samples. The Cu, Zn and Pb yields were higher than 99.2%, and isotopic fractionation did not occur during column separation. Copper and Zn delta values of AGV-2, BCR-2, BIR-1a, BHVO-2, GSP-2, NOD-A-1, NOD-P-1, DOLT-4, BCR-414, BCR-279 and NIST SRM 1573a were in good agreement with previously reported values. The intermediate measurement precision for Cu and Zn delta values was better than AE 0.02‰ (2s). The δ 65 Cu NIST976 , δ 66 Zn JMC and 206 Pb/ 207 Pb values determined in this study ranged from -0.19 to +0.73‰, -0.96 to +1.00‰ and 1.1172 to 1.2263, respectively. The δ 66 Zn JMC variability (Δ 66 Zn max-min ) in this study was relatively larger than that of δ 65 Cu NIST976 variability (Δ 65 Cu max-min ). A combination of Cu, Zn and Pb isotopes can be used as potential environmental tracers to track the origins of these elements in the environment as well as to understand their influence on organisms.

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