Ice cores from the relatively low-lying ice caps in Svalbard have not been widely exploited in climatic and environmental studies due to uncertainties about the effect of melt water percolation. However, results from two recent Svalbard ice cores, at Lomonosovfonna (1250 m asl) and Austfonna (750 m asl), have shown that with careful site selection, high-resolution sampling and multiple chemical analyses, it is possible to recover ice cores with partly preserved annual signals. These cores are estimated to cover at least the past 600 years and have been dated using a combination of known reference horizons and glacial modeling. The d 18 O data from both Lomonosovfonna and Austfonna ice cores suggest that the 20th century was the warmest during the past 600 years. A comparison of the ice core and sea ice records from this period suggests that sea ice extent and Austfonna d 18 O are linked over the past 400 years. This may reflect the position of the storm tracks and their direct influence on the relatively low altitude Austfonna. Lomonosovfonna may be less sensitive to such changes and primarily record atmospheric changes due to its higher elevation. The anthropogenic influence on Svalbard environment is illustrated by increased levels of non-sea-salt sulphate, nitrate, acidity, fly-ash and organic contaminants particularly during the second half of 1900s. Decreased concentrations of some components in recent decades most likely reflect emission and use restrictions. However, some current-use organic pesticide compounds show growing concentrations in near surface layers.
ABSTRACT. An updated compilation of published and new data of major-ion (Ca, Cl, K, Mg, Na, NO 3 , SO 4 ) and methylsulfonate (MS) concentrations in snow from 520 Antarctic sites is provided by the national ITASE (International Trans-Antarctic Scientific Expedition) programmes of Australia, Brazil, China, Germany, Italy, Japan, Korea, New Zealand, Norway, the United Kingdom, the United States and the national Antarctic programme of Finland. The comparison shows that snow chemistry concentrations vary by up to four orders of magnitude across Antarctica and exhibit distinct geographical patterns. The Antarctic-wide comparison of glaciochemical records provides a unique opportunity to improve our understanding of the fundamental factors that ultimately control the chemistry of snow or ice samples. This paper aims to initiate data compilation and administration in order to provide a framework for facilitation of Antarctic-wide snow chemistry discussions across all ITASE nations and other contributing groups. The data are made available through the ITASE web page (http:// www2.umaine.edu/itase/content/syngroups/snowchem.html) and will be updated with new data as they are provided. In addition, recommendations for future research efforts are summarized.
The Svalbard archipelago in arctic Norway receives considerable semivolatile organic contaminant (SOC) inputs from the atmosphere. To measure the history of net SOC accumulation there, we analyzed the upper 40 m of an ice core from Austfonna, the largest ice cap in Eurasia, for several legacy organochlorine (OC) compounds and currentuse pesticides (CUPs) including organophosphorus (OP), triazine, dinitroaniline, and chloroacetamide compounds. Five OP compounds (chlorpyrifos, terbufos, diazinon, methyl parathion, and fenitrothion), two OCs (methoxychlor and dieldrin), and metolachlorsan herbicideshad historical profiles in the core. The highest OC concentration observed was aldrin (69.0 ng L -1 ) in the surface sample (1992)(1993)(1994)(1995)(1996)(1997)(1998). The most concentrated OP was dimethoate (87.0 ng L -1 ) between 1986 and 1992. The surface sample also had highest concentrations of pendimethalin (herbicide, 18.6 ng L -1 ) and flutriafol, the lone observed fungicide (9.6 ng L -1 ). The apparent atmospheric persistence of CUPs likely results from little or no oxidation by OH • during the dark polar winter and in spring. Long-range atmospheric pesticide transport to Svalbard from Eurasia is influenced by the positive state of the North Atlantic Oscillation Index since 1980 and also by occasional fast-moving summer air masses from northern Eurasian croplands.
ABSTRACT. The Antarctic ice sheet preserves paleoclimate information in the form of physical and chemical stratigraphy. A deep ice core down to 2503 m depth was drilled at Dome Fuji station, East Antarctica, during the 1993^96 Japanese Antarctic Research Expedition inland operations. Oxygen isotope measurements were conducted on 50 cm long samples selected from the entire core length. A paleo-temperature profile was obtained for the past 340 ka by assuming the same conversion factors for the past relation as exist today between isotope ratio and both surface temperature and accumulation rate, in the inland region of Dronning Maud Land. The environmental-index profiles such as major chemical and dust contents coincide quite well withVostok ice-core data in general but not in detail. Detailed analysis of these climatic and environmental signals is in progress.
Mean net annual balance and the related spatio-temporal variations have been determined on the basis of well-dated artificial layers in shallow ice cores (Chernobyl, 1986, and atmospheric thermonuclear tests, mainly in 1961-62 in Novaya Zemlya). Seventy ice cores from 13 Svalbard glaciers have been analysed. On each glacier, in its accumulation area and at the highest elevation, one ice core was recovered down to about 40 m and sampled for radioactivity measurements to determine the 1986 and 1962-63 layer (1954 was the initial date of the nuclear tests). For each glacier, at least five complementary ice cores from the accumulation area were analysed to determine the Chernobyl reference layer. Six ice cores exhibit both the Chernobyl and nuclear tests layers and are of special interest in this study.This work provides new data on the deposition rates of natural and artificial radioisotopes. Using ice cores samples from the Arctic glaciers, even with superimposed ice accumulation, it is possible to distinguish between the Chernobyl and the nuclear tests fallouts. This work also shows that the mean annual net balance did not significantly change for at least five ice core locations in the Svalbard glaciers for the two periods extending from 1963 to 1986 and from 1986 to the recent date of drilling.
ABSTRACT. Snowpack and ice-core samples were collected from the dome of Austfonna ice cap, Svalbard, in the spring of both 1998 and 1999. The samples were analyzed for anions, cations, pH, liquid electrical conductivity and oxygen isotopes. Concentrations of chemical components in snowpack with a history of melting were much lower than those in unmelted snowpack. There was a clear difference between Mg 2+ /Na + ratios previously in melted snowpack (0.03 + 0.02) and in unmelted snowpack (0.11 +0.02).We propose that the Mg 2+ /Na + ratio can be used as an indicator of whether or not firn or bubbly ice in the Austfonna ice core has experienced melt percolation. The Mg 2+ /Na + ratio indicates that firn or bubbly ice prior to AD1920 was much less affected by melt percolation than firn or bubbly ice formed after 1920.
We have examined several MSA (methanesulfonic acid) records from the upper 200 m of the Antarctic ice sheet and in particular the new Dome F profile. At all the four sites studied, concentration profiles exhibit similar patterns as a function of depth. They suggest that snow metamorphism and solid phase migration are responsible for a marked release of gaseous MSA to interstitial firn air as well as probably to the free atmosphere, in particular at extremely low accumulation sites. Snow acidity can also modify MSA concentration. It is proposed that, below the upper few metres where the communication with the free atmosphere is possible, gaseous MSA may remain in the firn layers and be entrapped later in air bubbles at pore close‐off, i.e. when firn is transformed into ice. Chemical measurements on the firn core do not take into account the MSA released to the gaseous phase, but this fraction is measurable in ice samples. In spite of these alterations occurring in the firn layers, relative changes of the atmospheric MSA concentration in the past are probably still there deep within the Antarctic ice sheet. However, for glacial periods, different processes have to be considered in relation to modified aerosol properties.
Surface snow samples from the inland high plateau, East Queen Maud Land, Antarctica, show unique chemical characteristics. They are characterized by high acidity accompanying the high electrical conductivity, so that the hydrogen ion is the dominant ion, coupling with chloride and nitrate ions. The chemical composition differs sharply from sea salts. These characteristics appear more clearly than previously reported in Antarctica and are most strongly developed in snow samples from the high region. The tritium content increases in the inland high area, especially in the region higher than 3600 m asl (above sea level), which corresponds to the region where the effects of katabatic wind have vanished in the glaciological observations. The highest tritium content occurs in the vertical profile at a snow pit (3761 m asl, 77ø00'S, 35ø00'E), which corresponds to the snow deposition in 1966. The concentration is the highest ever reported in Antarctica and is almost as high as the one observed in the precipitation in the inland region of North America, which is the highest value ever reported in the world. All the results suggest that most of the ions contained in snow samples from the inland high plateau, especially higher than 3600 m asl, are not brought directly through the troposphere from the sea around Antarctica but from the higher atmosphere and that they are under the influence of the physicochemical reactions occurring there.1.
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