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S,S′-Bis(4-chlorophenyl) phosphorodithioate was useful for the synthesis of α,γ-dinucleoside 5′-triphosphates, G5′pppG and A5′pppA starting from the corresponding unprotected nucleoside 5′-phosphates under neutral conditions. G5′pppG was used for the synthesis of m7G5′pppG by means of the N7-methylation of one of two guanine moieties of G5′pppG.

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One-Pot Reaction for the Synthesis of m7G(5')pppG and m7G (5')pppA Using an Activatable Bifunctional Phosphorylating Reagent -(I). -(FUKUOKA, K.; SUDA, F.; SUZUKI, R.; TAKAKU, H.; ISHIKAWA, M.; HATA, T.; Tetrahedron