With its exceptional charge mobility, graphene holds great promise for applications in next-generation electronics. In an effort to tailor its properties and interfacial characteristics, the chemical functionalization of graphene is being actively pursued. The oxidation of graphene via the Hummers method is most widely used in current studies, although the chemical inhomogeneity and irreversibility of the resulting graphene oxide compromises its use in high-performance devices. Here, we present an alternative approach for oxidizing epitaxial graphene using atomic oxygen in ultrahigh vacuum. Atomic-resolution characterization with scanning tunnelling microscopy is quantitatively compared to density functional theory, showing that ultrahigh-vacuum oxidization results in uniform epoxy functionalization. Furthermore, this oxidation is shown to be fully reversible at temperatures as low as 260 °C using scanning tunnelling microscopy and spectroscopic techniques. In this manner, ultrahigh-vacuum oxidation overcomes the limitations of Hummers-method graphene oxide, thus creating new opportunities for the study and application of chemically functionalized graphene.
We report on the achievement of wafer-level photocatalytic overall water splitting on GaN nanowires grown by molecular beam epitaxy with the incorporation of Rh/Cr(2)O(3) core-shell nanostructures acting as cocatalysts, through which H(2) evolution is promoted by the noble metal core (Rh) while the water forming back reaction over Rh is effectively prevented by the Cr(2)O(3) shell O(2) diffusion barrier. The decomposition of pure water into H(2) and O(2) by GaN nanowires is confirmed to be a highly stable photocatalytic process, with the turnover number per unit time well exceeding the value of any previously reported GaN powder samples.
We have investigated the correlated surface electronic and optical properties of [0001]-oriented epitaxial InN nanowires grown directly on silicon. By dramatically improving the epitaxial growth process, we have achieved, for the first time, intrinsic InN both within the bulk and at nonpolar InN surfaces. The near-surface Fermi-level was measured to be ∼0.55 eV above the valence band maximum for undoped InN nanowires, suggesting the absence of surface electron accumulation and Fermi-level pinning. This result is in direct contrast to the problematic degenerate two-dimensional electron gas universally observed on grown surfaces of n-type degenerate InN. We have further demonstrated that the surface charge properties of InN nanowires, including the formation of two-dimensional electron gas and the optical emission characteristics can be precisely tuned through controlled n-type doping. At relatively high doping levels in this study, the near-surface Fermi-level was found to be pinned at ∼0.95-1.3 eV above the valence band maximum. Through these trends, well captured by the effective mass and ab initio materials modeling, we have unambiguously identified the definitive role of surface doping in tuning the surface charge properties of InN.
In this work, we present a general theoretical and numerical approach for simultaneously solving the photovoltage and photocurrent at semiconductor−liquid interfaces. Our methodology extends drift-diffusion methods developed for metal−semiconductor Schottky contacts in the device physics community into the domain of semiconductor− liquid "pseudo-Schottky" contacts. This model is applied to the study of photoelectrochemical anodes, utilized in the oxidative splitting of water. To capture both the photovoltage and photocurrent at semiconductor−liquid interfaces, we show that it is necessary to solve both the electron and hole current continuity equations simultaneously. The electron continuity equation is needed to primarily capture the photovoltage formation at photoanodes, whereas the hole continuity equation must be solved to obtain the photocurrent. Both continuity equations are solved through coupled recombination and generation terms. Moreover, to capture charge transfer at the semiconductor−liquid interface, floating (Neumann) boundary conditions are applied to the electron and hole continuity equations. As a model system, we have studied the illuminated hematite photoanode, where it is shown that our approach can capture band flattening during the formation of a photovoltage, as well as the photocurrent onset and saturation. Finally, the utility of this methodology is demonstrated by correlating our theoretical calculations with photocurrent measurements reported in the literature. In general, this work is intended to expand the scope of photocatalytic device design tools and thereby aid the optimization of solar fuel generation.
To model polaronic behavior in strongly correlated transition metal oxides with ab initio methods, one typically requires a level of theory beyond that of local density or general gradient density functional theory (DFT) approximations to account for the strongly correlated d-shell interactions of transition metal oxides. In the present work, we utilize density functional theory with additional on-site Hubbard corrections (DFT+U ) to calculate polaronic properties in two lithium ion battery cathode materials, LixFePO4 and LixMn2O4, and two photocatalytic materials, TiO2 and Fe2O3. We investigate the effects of the +U on-site projection on polaronic properties. Through systematic comparison with hybrid functional calculations, it is shown that +U projection in these model materials can impact upon the band gap, polaronic hopping barrier, and polaronic eigenstate offset from the band edges in a non-trivial manner. These properties are shown to have varying degrees of coupling and dependence on the +U projection in each example material studied, which has important implications for arriving at systematic material predictions of polaronic properties in transition metal oxides.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.