The reduction of oxygen at the cathode is one of the major bottlenecks of microbial fuel cells (MFCs). While research so far has mainly focused on chemical catalysis of this oxygen reduction, here we present a continuously wetted cathode with microorganisms that act as biocatalysts for oxygen reduction. We combined the anode of an acetate oxidizing tubular microbial fuel cell with an open air biocathode for electricity production. The maximum power production was 83 +/- 11 W m(-3) MFC (0.183 L MFC) for batch-fed systems (20-40% Coulombic yield) and 65 +/- 5 W m(-3) MFC for a continuous system with an acetate loading rate of 1.5 kg COD m(-3) day(-1) (90 +/- 3% Coulombic yield). Electrochemical precipitation of manganese oxides on the cathodic graphite felt decreased the start-up period with approximately 30% versus a non-treated graphite felt. After the start-up period, the cell performance was similar for the pretreated and non-treated cathodic electrodes. Several reactor designs were tested, and it was found that enlargement of the 0.183 L MFC reactor by a factor 2.9-3.8 reduced the volumetric power output by 60-67%. Biocathodes alleviate the need to use noble or non-noble catalysts for the reduction of oxygen, which increases substantially the viability and sustainability of MFCs.

The use of heavy gauge steel sheets for structural applications often requires a combination of high yield strength and adequate toughness. The most cost effective way to achieve high yield strength and high ductility in low alloyed steels is through grain refinement. In industrial practice, such refinement is commonly obtained by thermomechanical controlled processing (TMCP). This approach comprises slab reheating to well defined temperatures, a large amount of hot deformation below the non-recrystallisation temperature T-nr and accelerated cooling. In practice, the T-nr is generally raised by the addition of microalloying elements such as Nb and Ti. As these elements contribute substantially to the alloying costs, optimisation of their use allows for a decrease in production cost. Better understanding of the T-nr assists in tuning the rolling process so that optimum mechanical properties can be produced. One area of importance is to recognise that the concept of the T-nr was originally developed for reversing mills and the production of plate steels. Methods of defining and determining it must be modified if it is to be applied to strip mills and their associated short interpass times. The main goal of this review is to provide a concise and complete overview of the current understanding of the fundamental mechanisms that control the T-nr and to address the different methods that can be used to determine it

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This work studied the determination of the hydrogen fugacity during electrolytic charging. With a virgin surface, there were irregular permeation transients, attributed to irreproducible surface conditions. Cathodic pre-charging conditioned the entry side to a stable state. Permeability transients were used to measure the critical parameters in the thermodynamic relationship between hydrogen activity and electrochemical potential. At the same overpotenial, the hydrogen fugacity in the pH 12.6 0.1 M NaOH solution was higher than that in the pH 2 0.1M Na 2 SO 4 solution, attributed to differences in (i) the hydrogen evolution reaction, (ii) the surface state, and (iii) the true surface area.

Diclofenac, a nonsteroidal anti-inflammatory drug, is one of the most commonly detected pharmaceuticals in sewage treatment plant (STP) effluents. In this work, biologically produced manganese oxides (BioMnOx) were investigated to remove diclofenac. At neutral pH, the diclofenac oxidation with BioMnOx was 10-fold faster than with chemically produced MnO(2). The main advantage of BioMnOx over chemical MnO(2) is the ability of the bacteria to reoxidize the formed Mn(2+), which inhibits the oxidation of diclofenac. Diclofenac-2,5-iminoquinone was identified as a major transformation product, accounting for 5-10% of the transformed diclofenac. Except for 5-hydroxydiclofenac, which was identified as an intermediate, no other oxidation products were detected. Diclofenac oxidation was proportional to the amount of BioMnOx dosed, and the pseudo first order rate constant k was 6-fold higher when pH was decreased from 6.8 to 6.2. The Mn(2+) levels remained below the drinking water limit (0.05 mg L(-1)), thus indicating the efficient in situ microbiological regeneration of the oxidant. These results combined with previous studies suggest the potential of BioMnOx for STP effluent polishing.

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