Investigations concerning the processes of plugging stone structure formation, using X-ray diffraction, electronic microscopy and differential thermal analyses, were implemented. Influence of active mineral additives of metakaolin and zeolite on the properties of plugging mortar and their interaction with Portland cement minerals with the aid of the model systems were established.
In this paper, properties of concretes incorporating recycling waste and corrosion susceptibility of reinforcing steel bars were studied. It was established that fineness of ground granulated blast furnace slag (GGBFS) and fly ash (FA) and their simultaneous combination have an influence on the kinetics of strength development of Portland cements and concretes. The compressive strength of concrete containing 10% by mass of GGBFS and 10% by mass of FA even exceeds the compressive strength of control concrete by 6.5% and concrete containing 20% by mass of GGBFS by 8.8% after 56 days of hardening. The formation of the extra amount of ettringite, calcium hydrosilicates as well as hydroaluminosilicates causes tightening of a cement matrix of concrete, reducing its water absorption, and improving its resistance to freezing and thawing damage.
In this study, properties and peculiarities of hydration processes as well as paste microstructure of blended cements containing 10% by weight of natural zeolite were investigated. Free calcium hydroxide content, crystalline hydration products and microstructural architecture of hydrated cement pastes were examined by physical and chemical methods. It was found that the addition of natural zeolite provides formation of an extra amount of fine crystalline ettringite and tobermorite-like calcium hydrosilicates of CSH (B) type in the mineral non-clinker part of Portland cement resulting in strength synthesis of cement stone with high performance properties.
It has been shown that in the conditions of aggravation of ecological problems, shortage of high-quality raw materials for the production of Portland cement clinker a promising direction of cement industry development is more extensive waste utilization as well as production of low energy consuming cement clinker and modified composite cements, characterized by high content of active mineral additives. The use of modified composite cements both in mortars and concretes provides their high quality and durability and is of great social benefit in terms of resources preservation, energy saving, and environmental friendliness.
The hydraulic properties of ash from incinerated wastepaper sludge were investigated. It is shown that the phase composition of wastepaper sludge after heat treatment is similar to the classical fired carbonate-clay mixes. The necessity of using the combination of retarding admixtures with different action mechanism is shown. The strength in the initial hardening period is ensured by the formation of AFm-phases and ettringite, and subsequently by increasing the role of CSH.
Concrete block pavements have become an attractive engineering and economical alternative to both flexible and rigid pavements because of it’s high strength and durability. The influence of pozzolanic mineral additions – natural zeolite and expanded perlite powder on the properties of concrete interlocking blocks in different curing conditions has been studied. The use of zeolite as a substitute for cement in the production of concrete blocks increased the water demand but decreased the water absorption of the blocks. Obtained results show, that concrete blocks with 10% substitution of cement with zeolitic tuff is characterized by higher strength, lower mass loss and absence of efflorescence.
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