A solid oxide fuel cell (SOFC) system consists of a fuel cell stack with its auxiliary components. Modelling an entire SOFC system can be simplified by employing standard process flowsheeting software. However, no in-built SOFC module exists within any of the commercial flowsheet simulators. In Amiri et al. (Comput. Chem. Eng., 2015, 78:10-23), a rigorous SOFC module was developed to fill this gap. That work outlined a multi-scale approach to SOFC modelling and presented analyses at compartment, channel and cell scales. The current work extends the approach to stack and system scales. Two case studies were conducted on a simulated multilayer, planar SOFC stack with its balance of plant (BoP) components. Firstly, the effect of flow maldistribution in the stack manifold on the SOFC's internal variables was examined. Secondly, the interaction between the stack and the BoP was investigated through the effect of recycling depleted fuel. The results showed that anode gas recycling could be used for managing the gradients within the stack, while also improving fuel utilisation and water management.
Fuel processing for fuel cells has received considerable attention in the literature. However, most of the reported work focused on the production of hydrogen. With internal reforming fuel cells, the fuel processor can operate at relatively low temperatures to generate a mixture of gases containing hydrogen, methane, and the carbon oxides. The primary challenge for any fuel cell system is to select the most effective reforming scheme for a particular application considering factors such as electric efficiency, operating parameters, system complexity, and costs. In this paper we briefly review fuel processing technologies for fuel cells with particular emphasis on fuel pretreatment for internal reforming fuel cells, and discuss concepts and investigations we have pursued at Ceramic Fuel Cells, Ltd. (CFCL) on processing of gaseous and liquid hydrocarbons for application in CFCL’s solid oxide fuel cells.
Catalysis plays a critical role in solid oxide fuel cell systems. The electrochemical reactions within the cell--oxygen dissociation on the cathode and electrochemical fuel combustion on the anode--are catalytic reactions. The fuels used in high-temperature fuel cells, for example, natural gas, propane, or liquid hydrocarbons, need to be preprocessed to a form suitable for conversion on the anode-sulfur removal and pre-reforming. The unconverted fuel (economic fuel utilization around 85%) is commonly combusted using a catalytic burner. Ceramic Fuel Cells Ltd. has developed anodes that in addition to having electrochemical activity also are reactive for internal steam reforming of methane. This can simplify fuel preprocessing, but its main advantage is thermal management of the fuel cell stack by endothermic heat removal. Using this approach, the objective of fuel preprocessing is to produce a methane-rich fuel stream but with all higher hydrocarbons removed. Sulfur removal can be achieved by absorption or hydro-desulfurization (HDS). Depending on the system configuration, hydrogen is also required for start-up and shutdown. Reactor operating parameters are strongly tied to fuel cell operational regimes, thus often limiting optimization of the catalytic reactors. In this paper we discuss operation of an authothermal reforming reactor for hydrogen generation for HDS and start-up/shutdown, and development of a pre-reformer for converting propane to a methane-rich fuel stream.
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