Combining CO2 adsorption
and utilization in oxidative
dehydrogenation of ethane (ODHE) into a single bed is an exciting
way of converting a harmful greenhouse gas into marketable commodity
chemicals while reducing energy requirements from two-bed processes.
However, novel materials should be developed for this purpose because
most adsorbents are incapable of capturing CO2 at the temperatures
required for ODHE reactions. Some progress has been made in this area;
however, previously reported dual-functional materials (DFMs) have
always been powdered-state composites and no efforts have been made
toward forming these materials into practical contactors. In this
study, we report the first-generation of structured DFM adsorbent/catalyst
monoliths for combined CO2 capture and ODHE utilization.
Specifically, we formulated M-CaO/ZSM-5 monoliths (M = In, Ce, Cr,
or Mo oxides) by 3D-printing inks with CaCO3 (CaO precursor),
insoluble metal oxides, and ZSM-5. The physiochemical properties of
the monoliths were vigorously characterized using X-ray diffraction
(XRD), X-ray photoelectron spectroscopy (XPS), N2 physisorption,
elemental mapping, pyridine Fourier transform infrared spectroscopy
(Py-FTIR), H2-temperature-programmed reduction (H2-TPR), and NH3-temperature-programmed desorption (NH3-TPD). Their performances for combined CO2 adsorption
at 600 °C and ODHE reaction at 700 °C under 25 mL/min of
7% C2H6 were then investigated. The combined
adsorption/catalysis experiments revealed the best performance in
Cr-CaO/ZSM-5, which achieved 56% CO2 conversion, 91.2%
C2H4 selectivity, and 33.8% C2H4 yield. This exceptional performance, which was improved from
powdered-state DFMs, was attributed to the high acidity and numerous
oxidation states of the Cr2O3 dopant which were
verified by NH3-TPD and H2-TPR. Overall, this
study reports the first-ever proof-of-concept for 3D-printed DFM adsorbent/catalyst
materials and furthers the area of CO2 capture and ODHE
utilization by providing a simple pathway to structure these composites.
Magnetic induction has emerged as an attractive method for regenerating adsorbents during separation processes. In this work, we investigated the applicability of magnetic composite sorbents comprising Fe 2 O 3 and zeolite 13X in biogas upgrading via a magnetic induction process. The sorbent materials with 10, 15, and 20 wt % Fe 2 O 3 content were formulated into monolithic contactors via additive manufacturing and their physiochemical and magnetic properties were assessed accordingly. The effects of Fe 2 O 3 particle size, magnetic field intensity, and monolith composition and configuration on CO 2 and CH 4 desorption rates as well as heating and cooling rates were systematically investigated. Our results indicated that 5 μm-size Fe 2 O 3 with a loading of 20 wt % in the composite is the best performing material exhibiting heating, cooling, and desorption rates of 6.56 °C/min, 3.84 °C/min, and 0.25 mmol CO 2 /g min, respectively. It was also found that the layer-bylayer printing approach outperforms the homogenously mixed method in formulating magnetic monoliths by exhibiting heating, cooling, and desorption rates of 7.78 °C/min, 4.89 °C/min, and 0.376 mmol CO 2 /g min, respectively. Lastly, the advantage of induction heating over traditional heating in quickly regenerating the adsorbent was demonstrated. This work highlights the suitability of the induction heating method in upgrading biogas as a renewable source of energy.
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