Here we summarize recent progress in the development of electrolyte-gated transistors (EGTs) for organic and printed electronics. EGTs employ a high capacitance electrolyte as the gate insulator; the high capacitance increases drive current, lowers operating voltages, and enables new transistor architectures. Although the use of electrolytes in electronics is an old concept going back to the early days of the silicon transistor, new printable, fast-response polymer electrolytes are expanding the potential applications of EGTs in flexible, printed digital circuits, rollable displays, and conformal bioelectronic sensors. This report introduces the structure and operation mechanisms of EGTs and reviews key developments in electrolyte materials for use in printed electronics. The bulk of the article is devoted to electrical characterization of EGTs and emerging applications.
A free-standing polymer electrolyte called an ion gel is employed in both organic and inorganic thin-film transistors as a high capacitance gate dielectric. To prepare a transistor, the free-standing ion gel is simply laid over a semiconductor channel and a side-gate electrode, which is possible because of the gel's high mechanical strength.
The results presented in this work show for the first time that an electric field used to macroscopically align polymer nanofibers can also align polymer chains parallel to the fiber axis. This important result indicates that anisotropic structural properties (mechanical, electrical, etc.) can be induced in polymer nanofibers during the electrospinning process. Such uniaxially oriented nanofibers exhibit a variety of potential applications in biomedicine, microelectronics, and optics. A simple technique of vertical electrospinning with an electric field induced, stationary collection was employed to obtain the molecular orientation in polymer nanofibers. This manuscript describes the orientation process via electrospinning and verifies this molecular orientation in the polymer nanofibers using three independent methods: polarized Fourier transform infrared spectroscopy, polarized Raman scattering, and X-ray diffraction.
The effects of composition, temperature, and polymer identity on the electrical and viscoelastic properties of block copolymer-based ion gels were investigated. Ion gels were prepared through the self-assembly of poly(styrene-b-ethylene oxide-b-styrene) (SOS) and poly(styrene-b-methyl methacrylate-b-styrene) (SMS) triblock copolymers in a room-temperature ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethylsufonyl)imide ([EMI][TFSI]). The styrene end-blocks associate into micelles, whereas the ethylene oxide and methyl methacrylate midblocks are well-solvated by this ionic liquid. The properties of the ion gels were examined over the composition range of 10−50 wt % polymer and temperature range of 25−160 and 25−200 °C for the SOS- and SMS-based gels, respectively. The response of the ion gels to ac electric fields below 1 MHz can be represented by a resistor and constant phase element (CPE) series circuit, with a characteristic time corresponding to the establishment of stable electrical double layers (EDLs) at the gel/electrode interfaces. The ionic conductivity and specific capacitance were found to range from 3 × 10−5 to 3 × 10−2 S/cm and 0.3 to 10 μF/cm2, respectively. For 1 mm thick gels, the corresponding RC time constants ranged from 2 × 10−5 to 5 × 10−3 s. Notably, at high polymer concentrations, the ionic conductivity is much higher in SOS than SMS due to the higher glass transition of the methyl methacrylate block. Two relaxation modes have been observed in the ion gels under oscillatory mechanical shear. The faster mode corresponds to the relaxation of the midblocks in the ionic liquid, while the slow mode reflects motion of the end-blocks within their micellar cores. The plateau modulus of the gels was found to vary from 0.5 to 100 kPa over the measured composition and temperature ranges. While the ionic conductivity generally decreases as the modulus increases, it is possible to achieve conductivities greater than 0.01 S/cm with moduli above 10 kPa in the SOS system.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.