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This study presents a geochemical framework and geographic information system (GIS) method for assessing the intrinsic potential of surface water and groundwater to mobilize arsenic, molybdenum, selenium, uranium, and vanadium. The method was created using published groundwater and surface water geochemical data from the National Uranium Resource Evaluation database for 2302 groundwater and 915 surface water samples. The method was evaluated using published groundwater geochemical data from the Texas Water Development Board. Geochemical data were analyzed in GIS. Samples were categorized by environmental condition, which was determined by using reduction–oxidation—as indicated by pe—and pH ranges for each sample based on geochemical mobility frameworks developed by Smith (2007) and Perel’man (1986). Reduction–oxidation and pH influence the occurrence, persistence, and mobility of arsenic, molybdenum, selenium, uranium, and vanadium in groundwater and surface water. Reduction–oxidation categories were assigned to water samples using concentrations of redox-active constituents, including dissolved oxygen, iron, manganese, and sulfur. The presence of iron substrates and hydrogen sulfides were considered in relation to mobility mechanisms. Twelve-digit hydrologic unit code (HUC) boundaries were used in GIS as analysis areas to determine the most commonly occurring environmental condition in each HUC. The resulting maps identify the environmental conditions in different areas that can be used to identify where the elements are mobile. This methodology provides a systematic approach to identify areas where elements in groundwater and surface water may occur and persist and may be transferable to other locations.

: The introduction of nutrients from chemical fertilizer, animal manure, wastewater, and atmospheric deposition to the eastern Iowa environment creates a large potential for nutrient transport in watersheds. Agriculture constitutes 93 percent of all land use in eastern Iowa. As part of the U.S. Geological Survey National Water Quality Assessment Program, water samples were collected (typically monthly) from six small and six large watersheds in eastern Iowa between March 1996 and September 1997. A Geographic Information System (GIS) was used to determine land use and quantify inputs of nitrogen and phosphorus within the study area. Streamliow from the watersheds is to the Mississippi River. Chemical fertilizer and animal manure account for 92 percent of the estimated total nitrogen and 99.9 percent of the estimated total phosphorus input in the study area. Total nitrogen and total phosphorus loads for 1996 were estimated for nine of the 12 rivers and creeks using a minimum variance unbiased estimator model. A seasonal pattern of concentrations and loads was observed. The greatest concentrations and loads occur in the late spring to early summer in conjunction with row‐crop fertilizer applications and spring nmoff and again in the late fall to early winter as vegetation goes into dormancy and additional fertilizer is applied to row‐crop fields. The three largest rivers in eastern Iowa transported an estimated total of 79,000 metric tons of total nitrogen and 6,800 metric tons of total phosphorus to the Mississippi River in 1996. The estimated mass of total nitrogen and total phosphorus transported to the Mississippi River represents about 19 percent of all estimated nitrogen and 9 percent of all estimated phosphorus input to the study area.

A previously completed mineral resources assessment of the Texas Coastal Plain indicated the potential for the future discovery of uranium resources. Geoenvironmental assessments that include the hydrogeologic framework can be used as a tool to understand the potential effects of mining operations. The hydrogeologic framework for this study focused on the composite hydrogeologic unit of the tract permissive for the occurrence of uranium consisting of the upper part of the Miocene-age Fleming Formation/Lagarto Clay, Pliocene-age Goliad and Pleistocene-age Willis Sands, Pleistocene-age Lissie and Beaumont Formations, and Holocene-age alluvial sediments (fluvial alluvium and eolian sand deposits). This composite hydrogeologic unit, which contains the Chicot and Evangeline aquifers of the Gulf Coast aquifer system, is intended for inclusion in a regional-scale geoenvironmental assessment of as yet undiscovered uranium resources. This article provides (1) a brief literature review describing the geologic and hydrogeologic settings, (2) the methodology used to develop a composite hydrogeologic framework, and (3) descriptions and maps of the land-surface altitude, composite hydrogeologic unit base and midpoint depth, water-level altitude, depth of water, unsaturated and saturated zone thickness, and transmissivity and hydraulic conductivity. A composite hydrogeologic unit, created by combining geologic and hydrogeologic data and maps for individual geologic and hydrogeologic units, is intended for use as a tool in a geoenvironmental assessment to evaluate potential contaminant migration through various avenues. Potential applications include using the hydrogeologic framework as an input into a geoenvironmental assessment to help estimate the potential for (1) runoff of contaminants into surface water, (2) infiltration of contaminants into the groundwater (aquifers), or (3) movement of contaminants from the mining area through wind, groundwater-flow, or streamflow in a given permissive tract. The procedures outlined in this paper also provide a method for developing hydrogeologic frameworks that can be applied in other areas where mining may occur.

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