This work aims to understand the physicochemical properties of potato starch nanoparticles (SNPs) obtained by anti‐solvent precipitation. Moisture content, water activity, color, morphology, thermal behavior (differential scanning calorimetry), swelling factor, solubility in water, water sorption isotherms, rheological properties, and stability in water are analyzed and compared using native potato starch (PS) as control. The resulting SNPs after anti‐solvent precipitation have a particle size between 50 and 150 nm, smaller than those observed in PS (between 10 and 100 µm). SNPs behave as an amorphous material without gelatinization stage where the swelling factor is drastically reduced, while the solubility increased dramatically at low temperatures when compared with PS. The Guggenheim–Anderson–de Boer model from the isotherms data allows a calculation of the surface area, obtaining values of 105 and 211 m2 g−1 for PS and SNPs, respectively. The high surface area in SNPs is associated with an increase in the proportion of hydroxyl groups active for water adsorption throughout its structure. Both samples show Newtonian fluid behavior; however, SNPs solutions prove to be much more stable at room temperature than PS solution.

This study aims to develop and characterize modified starch particles containing anthocyanins (ACNs) from jambolan (Syzygium cumini) fruit, produced by an anti‐solvent precipitation method. Trapping efficiency, particle size distribution, surface charge, crystalline structure, chemical bonds, thermal properties, moisture content, water activity, color, and desorption experiments are carried out in modified cassava starch (MCS) and modified potato starch (MPS), both containing ACNs. Physicochemical properties of MCS and MPS both containing ACN (MCS‐ACN and MPS‐ACN) are compared using native cassava and potato starches, as well as modified cassava and potato starches without ACNs. ACNs are trapped into the modified starches and the trapping efficiency value oscillates between 9.89% and 12.37%. The resulting MCS‐ACN and MPS‐ACN‐ powders display bimodal distributions with particle size lower than 900 nm and amorphous structure. Furthermore, the MCS‐ACN and MPS‐ACN powders show red color typical of ACNs and they are completely soluble in water and acidified water solutions at room temperature. This research reports for the first‐time, information regarding the stabilization of ACNs using modified starch particles.

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