Kenneth J. Wiesinger scite author profile

ChemInform Abstract The structures of the trichlorodimolybdenum complex (IV) (space group P21/c, Z=4) and of the title complexes (VIa) (C2/c, Z=4) and (VIb) (yield ca. 30%; P2/c, Z=4) are determined by X-ray analysis. The Mo-C distances in (IV) and (VIa) are compared to those of other Mo2X4(PR3)4 compounds, and it is shown that the Mo atom in such compounds displays an essentially constant covalent radius of 1.40 ±0.02å.

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Decakis(Acetonitrile)Dimolybdenum(II) Tetrafluoroborate(1—)

Cotton

Wiesinger

1992

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Kenneth J. Wiesinger

Synthesis and characterization of octaacetonitriledimolybdenum(II) tetrafluoroborate

Synthesis and characterization of molybdenum species: dinuclear and mononuclear species of the molecular formulas [Mo2(O2CCH3)2(LL)2][BF4]2 and [Mo(O)(F)(LL)2][BF4] where LL=bis-phosphine. The use of [Mo2(NCCH3)10][BF4]4 as a source for the [Mo2]4+ core

Mo2F4(PR3)4 compounds and a comparison of their properties with those of other Mo2X4(PR3)4 compounds. A new synthetic route to metal fluorides by the reaction of alkyl species with Olah's reagent

Structures of Mo2(CH3)4(PR3)4 molecules: constancy of covalent radius of molybdenum in these and other Mo2X4(PR3)4 molecules

Decakis(Acetonitrile)Dimolybdenum(II) Tetrafluoroborate(1—)

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