The effects of addition of neutral salts on the cholesteric mesophase structure and optical properties of aqueous solutions of hydroxypropyl cellulose (HPC) were investigated by spectrophotometry and an NMR technique with D 2 O as solvent. In the measurements of selective light-reflection spectra, the wavelength of maximal reflectance and therefore the cholesteric helical pitch (P), too, varied systematically with a change in strength of a socalled "chaotropic" effect of the additive salts; i.e., their effectiveness in increasing P was pronounced in the order of Cl −
The Arctic Ocean is known to be quiescent in terms of turbulent kinetic energy (TKE) associated with internal waves. To investigate the current state of TKE in the seasonally ice-free Chukchi Plateau, Arctic Ocean, this study performed a 3-week, fixed-point observation (FPO) using repeated microstructure, hydrographic, and current measurements in September 2014. During the FPO program, the microstructure observation detected noticeable peaks of TKE dissipation rate ε during the transect of an anticyclonic eddy moving across the FPO station. Particularly, ε had a significant elevation in the lower halocline layer, near the critical level, reaching the order of 10 -8 W kg -1 . The ADCP-measured current displayed energetic near-inertial internal waves (NIWs) propagating via the stratification at the top and bottom of the anticyclone. According to spectral analyses of horizontal velocity, the waves had almost downward energy propagation, and its current amplitude reached ~10 cm s −1 . The WKB scaling, incorporating vertical variations of relative vorticity, suggests that increased wave energy near the two pycnoclines was associated with diminishing group velocity at the corresponding depths. The fine-scale parameterization using observed near-inertial velocity and buoyancy frequency successfully reproduced the characteristics of observed ε, supporting that the near-inertial kinetic energy can be effectively dissipated into turbulence near the critical layer. According to a mixed layer slab model, a rapidly moving storm that has passed over in the first week likely delivered the bulk of NIW kinetic energy, eventually captured by the vortex, into the surface water. References Kawaguchi, Y., S. Nishino, J. Inoue, K. Maeno, H. Takeda, and K. Oshima, Enhanced diapycnal mixing due to near-inertial internal waves propagating through an
A land process model [the coupled hydrological and biogeochemical model (CHANGE)] is used to quantitatively assess changes in the ice phenology, thickness, and volume of terrestrial Arctic rivers from 1979 to 2009. The CHANGE model was coupled with a river routing and discharge model enabling explicit representation of river ice and water temperature dynamics. Model-simulated river ice phenological dates and thickness were generally consistent with in situ river ice data and landscape freeze–thaw (FT) satellite observations. Climate data indicated an increasing trend in winter surface air temperature (SAT) over the pan-Arctic during the study period. Nevertheless, the river ice thickness simulations exhibited a thickening regional trend independent of SAT warming, and associated with less insulation and cooling of underlying river ice by thinning snow cover. Deeper snow depth (SND) combined with SAT warming decreased simulated ice thickness, especially for Siberian rivers, where ice thickness is more strongly correlated with SND than SAT. Overall, the Arctic river ice simulations indicated regional trends toward later fall freezeup, earlier spring breakup, and consequently a longer annual ice-free period. The simulated ice phenological dates were significantly correlated with seasonal SAT warming. It is found that SND is an important factor for winter river ice growth, while ice phenological timing is dominated by seasonal SAT. The mean total Arctic river ice volume simulated from CHANGE was 54.1 km3 based on the annual maximum ice thickness in individual grid cells, while river ice volume for the pan-Arctic rivers decreased by 2.82 km3 (0.5%) over the 1979–2009 record. Arctic river ice is shrinking as a consequence of regional climate warming and coincident with other cryospheric components, including permafrost, glaciers, and sea ice.
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