The regioregular highly head-to-tail-coupled poly(3-alkylthiophene) (HT-P3AT) films were
prepared by a friction-transfer technique. Polarized UV−vis absorption spectroscopy and grazing incidence
X-ray diffraction (GIXD) were used to study the polymer molecular arrangement in the friction-transferred
HT-P3AT films, and scanning electron microscopy (SEM) was used to observe the film surface morphology.
The polarized UV−vis absorption spectra show a large dichroism regarding the drawing direction of
friction-transfer. The order parameter is evaluated close to unity, which is the ideal orientation state.
GIXD measurements show that alkyl side chains lie in the film plane, and the polymer backbones are
well-ordered along the drawing direction of friction-transfer within 10° for poly(3-hexylthiophene) and
13° for poly(3-dodecylthiophene) in the film plane. The polymer backbones form a layered structure with
the stacking of thiophene rings normal to the film surface. The polymer molecules in the friction-transferred films are ideally arranged three-dimensionally.
A comparative study in molecular arrangements of the n-octadecyltrichlorosilane (OTS) monolayer prepared by the Langmuir method and the chemisorption methods were carried out on the basis of grazing incidence X-ray diffraction (GIXD) and X-ray reflectivity (XR) measurements. The OTS molecules in the Langmuir OTS monolayer uniformly tilt ca. 8-10°to the surface normal and packed in a hexagonal lattice with the (10) spacing of 0.412 nm. On the other hand, the OTS molecules in the chemisorbed OTS monolayer tilt ca. 15-17°to the surface normal and also crystallite orient randomly in the two-dimensional plane. The average magnitude of the (10) spacing of the chemisorbed OTS monolayer was ca. 0.417 nm. Direct evidence that the packing density of the Langmuir OTS monolayer was higher than that of the chemisorbed OTS monolayer was obtained by GIXD and XR measurements for the first time.
A small-angle x-ray scattering technique has been applied for characterizing pore-size distribution in porous low-κ dielectric films. The data are collected in reflection geometry using offset θ/2θ scans for avoiding strong specular reflections from the film surface and its substrate. The effects of refraction and reflection at the film surface and interface are corrected by the distorted wave Born approximation. A Γ-distribution mode is used to determine the pore-size distribution in a film. The technique has been used to analyze porous methyl silsesquioxane films. The pore sizes were found to disperse in the range from subnanometer to several nanometers, and the results agree well with those obtained by the N2 gas adsorption technique.
Additional information by EDL about the tumor stage in gastric cancer led to a modification of the therapeutic strategy in 40% of patients, in spite of earlier comprehensive diagnostic work-up using modern imaging procedures. EDL should therefore be mandatory if neoadjuvant treatment is planned, in order to avoid either undertreatment or overtreatment of this type of tumor.
A monolayer film of unilamellar titania crystallites consisting of two planes of Ti/O atoms and two additional
planes of O atoms underwent an interesting structural change by heat treatment at 800 °C and above to produce anatase
nanocrystals oriented along the c-axis. This phenomenon is distinct from phase transformation of the bulk phase in terms
of the significantly higher crystallization temperature of anatase and the preferential orientation of nanocrystals. This
may be peculiar to two-dimensional nanosystems, providing a new route for the fabrication of oriented nanocrystals.
Endoscopic stapling diverticulostomy (ESD) using an endostapler is a modification of the standard endoscopic treatment of Zenker's diverticulum (ZD). It is characterized by complete myotomy of the upper esophageal sphincter, with division of the common wall between diverticulum and esophagus, followed by immediate simultaneous closure of the divided edges with the staples. ESD was performed on 21 patients with ZD between January 1996 and October 1997. The results were then evaluated. Operation time averaged 22 min. Wide opening of the diverticulum and excellent hemostasis were achieved. All of the patients but one, who died postoperatively of myocardial infarction, resumed oral intake without any evidence of cervical sepsis or mediastinitis. Complete relief of dysphagia was achieved in all 20 patients. Hospital stay averaged 4.7 days (range, 2-7 days). The patients were followed up after ESD for a median time period of 12 months. No relapses were recorded. ESD is an effective endoscopic treatment for ZD that entails a low risk of complications and requires only a short period of hospitalization.
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