Perovskite LaFeO3 is one of the most useful materials for the application in a catalyst, gas sensors, and fuel cells, etc. LaFeO3 nanoparticles were synthesized by the citrate sol-gel method. According to the TG-DTA analysis on LaFeO3 xerogel powder, the proper crystallization temperature was found to be at 450 °C. The TEM images also show clear crystal formation was started at 450 °C. The LaFeO3 nanocrystalline particles were obtained by sintering the calcined powders at different temperatures (800 °C, 900 °C, and 1000 °C) for 4 hours. The resulting particles were characterized by XRD, EDXRF, FT IR, and SEM analysis. At 900 °C, the XRD pattern of LaFeO3 shows an orthorhombic crystal structure. The average crystallite sizes vary between 30-60 nm and the increase in crystallite size with increasing sintering temperatures and it may be due to the increase in grain growth. FT IR analysis shows strong La-O and Fe-O vibrations. Based on the XRD and FT IR data, the optimum sintering temperature was chosen at 900 °C. The SEM micrographs show that the morphology of LaFeO3 has small-sized grains with round shape. The optical properties were determined by UV-visible spectroscopy in the wavelength range of 300 nm-700 nm. The optical band gap energy values of LaFeO3 using Tauc’s plot were found to be about 2.45 eV. These results indicate that the LaFeO3 prepared by the sol-gel method has a relatively lower band gap value and so it can have the potential for photocatalytic applications.