Multichromophoric triads 1 and 2 based on aza-BODIPY as central chromophore and bay-substituted (tetrachloro- and tetraphenoxy-)perylenediimides (PDI) as peripheral chromophores have been designed and synthesized that are panchromatic absorbers and...

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RGB antennae consisting of naphthalimides, perylenediimides and aza-BODIPY with efficient FRET show unique ratiometric temperature sensing, metal sensing (FRET-off) and pH sensing through various stimuli sensitive band tuning.

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Designing new donor-acceptor systems and probing their energy/electron transfer dynamics is essential in the context of development of biomimetic photosynthetic systems. In this work, we have designed, synthesized and characterized...

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Recently developed C10‐(H)‐arylated‐N‐(pyren‐1yl)‐picolinamide compounds have been investigated spectroscopically for their photophysical properties and metal ion sensing abilities. Two sets of regioisomers were selected based on their molar absorptivities and fluorescence quantum yields and classified into two series I methoxy group at meta‐ and para‐ position of phenyl ring, and series II methyl group at meta‐ and para‐ position of phenyl ring. Additionally, for better understanding on structure‐property relationship, a comparison study with C‐10 unsubstituted compound was also conducted. All compounds exhibited characteristic absorption and emission responses only towards Cu2+ and Fe3+ ions among all the screened metals. While the reference compound and those with methoxy substituent displayed a fluorescence turn‐off behaviour, compounds with methyl groups showed fluorescence turn‐on response through excimer formation at ∼550 nm in the presence of Cu2+ and Fe3+. Sensing studies were performed to elucidate structure‐property relationship and to obtain limits of detection, binding constants and fluorescence quenching constants. Temperature‐dependent fluorescence studies were performed to distinguish the type of excimers produced by two compounds in series II with the metal ions.

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