Sodium silicate‐activated slag‐fly ash binders (SFB) and slag‐metakaolin binders (SMKB) are room‐temperature hardening binders that have excellent mechanical properties and a significantly lower carbon footprint than ordinary Portland cement (OPC). The aim of this study was to use nuclear magnetic resonance (NMR) spectroscopy to study the nanostructure of poorly ordered phases in SFB by varying slag/fly ash ratio, curing time, and curing temperature. Fly ash was completely substituted with metakaolin and the effect of this substitution on the poorly ordered phases was studied. It was observed that the proportion of geopolymer was generally higher in SMKB when compared to SFB. Although C–N–A–S–H and geopolymer coexisted in SFB and SMKB, C–N–A–S–H was the major product phase formed. The mean chain length (MCL) and the structure of C–N–A–S–H gel were estimated as a function of time, temperature, and slag/fly ash ratio. The MCL was found to have a negative correlation with slag/fly ash ratio and Ca/(Si+Al) ratio, but positive correlation with curing temperature. The average Si/Al atom ratios for geopolymers were also estimated. Lastly, the increased proportion of five‐coordinated aluminum (Al(V)) in metakaolin resulted in the decreased unreacted metakaolin in the hardened binder but did not increase the geopolymer content.
Alkali silicate activated slag and class F fly ash‐based binders are ambient curing, structural materials that are feasible replacements for ordinary Portland cement (OPC). They exhibit advantageous mechanical properties and less environmental impact than OPC. In this work, five sodium silicate activated slag‐fly ash binder mixtures were developed and their compressive and flexural strengths were studied as a function of curing temperature and time. It was found that the strongest mixture sets at ambient temperature and had a Weibull average flexural strength of 5.7 ± 1.5 MPa and Weibull average compressive strength of 60 ± 8 MPa at 28 days. While increasing the slag/fly ash ratio accelerated the strength development, the cure time was decreased due to the formation of calcium silicate hydrate (C–S–H), calcium aluminum silicate hydrate (C–A–S–H), and (Ca,Na) based geopolymer. The density, microstructure, and phase evolution of ambient‐cured, heat‐cured, and heat‐treated binders were studied using pycnometry, scanning electron microscopy, energy dispersive X‐ray spectroscopy (SEM‐EDS), and X‐ray diffraction (XRD). Heat‐cured binders were more dense than ambient‐cured binder. No new crystalline phases evolved through 28 days in ambient‐ or heat‐cured binders.
Sodium silicate activated, slag‐fly ash binders are potential alternative binders to Portland cement. In this study, the early age properties of slag‐fly ash binders namely, set time, and heats of reaction were investigated. Set time was investigated using a combination of two methods namely, the ASTM C403 penetration testing, and s‐wave ultrasonic wave reflectometry (SUWR). The discrepancy in set time identified by these two methods suggested the presence of a soft gel which eventually hardened with time. The composition of this soft gel was analyzed by suspending the chemical reaction of the binder after the soft gel formed, but before it hardened. In order to analyze the composition of the soft gel, selective chemical extractions were performed on the binder. 29Si Magic Angle Spinning‐Nuclear Magnetic Resonance (MAS‐NMR), and FTIR spectroscopy were performed on binders and extraction residues. The soft gel contained a modified calcium silicate hydrate gel (C–N–S–H where N=Na), with a short mean chain length and no observable Al incorporation. Orthosilicate units were also found to be present in relatively high proportions when compared to hardened binders at later ages.
Bamboo is a fast-growing, readily available natural material with tensile specific strength equivalent to that of steel (250-625 MPa/g/cm 3 ). In the pursuit of sustainable construction materials, a composite was made with potassium polysialate siloxo geopolymer as the matrix and randomly oriented chopped bamboo fibers (Guadua angustifolia) from the Amazon region as the reinforcement. Four-point flexural strength testing of the geopolymer composite reinforced with bamboo fibers was carried out according to ASTM standard C78/C78M-10 e1. Potassiumbased metakaolin geopolymer reinforced with 5 wt% (8 vol%) untreated bamboo fibers yielded 7.5 MPa four-point flexural strength. Scanning electron microscopy and optical microscopy were used to investigate the microstructure. In addition, X-ray diffraction was used to confirm the formation of geopolymer. the relationships between composition, processing, microstructure, and the properties of metakaolin-based geopolymers (MKGPs) and found that the best compressive strength is obtained when the Si:Al molar ratio is 2:1 in geopolymers. When compared to ordinary portland cement (OPC), geopolymers have faster setting time and lower density. The mechanical properties of geopolymers are superior to portland cement in general, but are influenced by the contents of the liquid phase in the mixture, the curing temperature, and the final porosity of the body. 5 The energy required to produce geopolymer is considerably lower than that required for OPC. The extent of reduction in energy depends upon the raw materials used to make the geopolymer. 7 They are processed as a liquid enabling them to be cast into any shape and cured at ambient or slightly elevated temperatures. However, like ceramics, pure geopolymers are brittle and are weak in tension. Their failure is catastrophic with very little warning signal. On the other hand, they can
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