The magnetic anisotropy associated with a pentagonal bipyramidal coordination sphere is examined on the basis of experimental and theoretical investigations; effects of crystal field, structural distortion, and second coordination sphere are discussed.
The first example of a ferromagnetic Ni(ii)–Cr(iii) single-chain magnet fashioned using pentagonal bipyramidal Ni(ii) complexes with Ising-type anisotropy.
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