Lubrication theory for unstable thin liquid films on solid substrates is used to model the coarsening dynamics in the long-time behavior of dewetting films. The dominant physical effects that drive the fluid dynamics in dewetting films are surface tension and intermolecular interactions with the solid substrate. Instabilities in these films lead to rupture and other morphological changes that promote nonuniformity in the films. Following the initial instabilities, the films break up into near-equilibrium droplets connected by an ultrathin film. For longer times, the fluid will undergo a coarsening process in which droplets both move and exchange mass on slow time scales. The dynamics of this coarsening process will be obtained through the asymptotic reduction of the long-wave PDE governing the thin film to a set of ODEs for the evolution of the droplets. From this, a scaling law that governs the coarsening rate is derived.

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Electrowetting has recently been explored as a mechanism for moving small amounts of fluids in confined spaces. We propose a diffuse-interface model for drop motion, due to electrowetting, in a Hele-Shaw geometry. In the limit of small interface thickness, asymptotic analysis shows that the model is equivalent to Hele-Shaw flow with a voltage-modified Young-Laplace boundary condition on the free surface. We show that details of the contact angle significantly affect the time scale of motion in the model. We measure receding and advancing contact angles in the experiments and derive their influence through a reduced-order model. These measurements suggest a range of time scales in the Hele-Shaw model which include those observed in the experiment. The shape dynamics and topology changes in the model agree well with the experiment, down to the length scale of the diffuse-interface thickness.

A configuration of near-equilibrium liquid droplets sitting on a precursor film which wets the entire substrate can coarsen in time by two different mechanisms: collapse or collision of droplets. The collapse mechanism, i.e., a larger droplet grows at the expense of a smaller one by mass exchange through the precursor film, is also known as Ostwald ripening. As was shown by K. B. Glasner and T. P. Witelski (‘Collision versus collapse of droplets in coarsening of dewetting thin films’, Phys. D209 (1–4), 2005, 80–104) in case of a one-dimensional substrate, the migration of droplets may interfere with Ostwald ripening: The configuration can coarsen by collision rather than by collapse. We study the role of migration in a two-dimensional substrate for a whole range of mobilities. We characterize the velocity of a single droplet immersed into an environment with constant flux field far away. This allows us to describe the dynamics of a droplet configuration on a two-dimensional substrate by a system of ODEs. In particular, we find by heuristic arguments that collision can be a relevant coarsening mechanism.

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