Water samples were collected from 24 public-supply wells and 13 private residential wells during the summer of 2003 and analyzed to describe the chemical quality of ground water throughout the Chemung River basin, upgradient from Waverly, N.Y, on the Pennsylvania border. Wells were selected to represent areas of heaviest groundwater use and greatest vulnerability to contamination, and to obtain a geographical distribution across the 1,130 square-mile basin. Samples were analyzed for physical properties, inorganic constituents, nutrients, metals and radionuclides, pesticides, volatile organic compounds, and bacteria. The cations that were detected in the highest concentrations were calcium and sodium; the anions that were detected in the greatest concentrations were bicarbonate, chloride, and sulfate. The predominant nutrient was nitrate. Nitrate concentrations in samples from wells finished in sand and gravel were greater than in those from wells finished in bedrock, except for one bedrock well, which had the highest nitrate concentration of any sample in this study. The most commonly detected metals were aluminum, barium, iron, manganese, and strontium. The range of tritium concentrations (0.6 to 12.5 tritium units) indicates that the water ages ranged from less than 10 years old to more than 50 years old. All but one of the 15 pesticides detected were herbicides; those detected most frequently were atrazine, deethylatrazine, and two degradation products of metolachlor (metachlor ESA and metachlor OA), which were the pesticides detected at the highest concentrations. Not every sample collected was analyzed for pesticides, and pesticides were detected only in wells finished in sand and gravel. Volatile organic compounds were detected in 15 samples, and the concentrations were at or near the analytical detection limits. Total coliform were detected in 12 samples; fecal coliform were detected in 7 samples; and Escherichia coli was detected in 6 samples. These bacteria were detected in water from bedrock as well as sand-and-gravel aquifers. Federal and State water-quality standards were exceeded in several samples. Two samples exceeded the chloride U.S. Environmental Protection Agency Secondary Maximum Contaminant Level of 250 milligrams per liter. The U.S. Environmental Protection Agency Drinking Water Advisory for sodium (30 to 60 milligrams per liter) was exceeded in 11 samples. The upper limit of the Secondary Maximum Contaminant Level range for aluminum (200 micrograms per liter) was exceeded in one sample. The Maximum Contaminant Level for barium (2,000 micrograms per liter) was exceeded in one sample. The Secondary Maximum Contaminant Level for iron (300 micrograms per liter) was exceeded in 11 samples. The Secondary Maximum Contaminant Level for manganese (50 micrograms per liter) was exceeded in 20 samples. The proposed Maximum Contaminant Level for radon (300 picocuries per liter) was exceeded in 34 samples.
Two water-production systems, one for the Village of Pulaski and the other for the Villages of Sandy Creek and Lacona in Oswego County, New York, withdraw water from the Tug Hill glacial-drift aquifer, a regional sand and gravel aquifer along the western flank of the Tug Hill Plateau, and provide the sole source of water for these villages. As a result of concerns about contamination of the aquifer, two studies were conducted during 2001 to 2004, one for each waterproduction system, to refine the understanding of groundwater flow surrounding these water-production systems. Also, these studies were conducted to determine the cause of the discrepancy between groundwater ages estimated from previously constructed numerical groundwater flow models for the Pulaski and Sandy Creek/Lacona well fields and the apparent groundwater ages determined using concentrations of tritium and chlorofluorocarbons.
This set of maps and geohydrologic sections depicts the geology and hydrology of valley-fill aquifers in the 14-mile reach of the Chenango River valley between the Village of Greene and the Chenango Valley State Park, N.Y. It depicts the aquifers; locations of domestic, production, and test wells; surficial geology; water-table altitude; potentiometric-surface altitude; generalized saturated thickness of the unconfined (water-table) aquifer; generalized thickness of the confined aquifer; and includes three geohydrologic sections.The valley fill in the Chenango River valley consists primarily of (1) glaciofluvial deposits comprised of stratified coarse-grained sediment (sand and gravel) that were deposited by meltwater streams flowing on, below, and in front of a glacier; (2) lacustrine sediments consisting of stratified fine-grained sediment (very fine sand, silt, and clay) that were deposited in proglacial lakes that formed at the front of a glacier; and (3) recent alluvium consisting of alluvial fan deposits (sand, silt, and gravel), floodplain sediments (fine-to-medium sand and silt), and channel deposits (sand and gravel).The Chenango River valley contains an unconfined valley-fill aquifer throughout much of the study area, and a confined valley-fill aquifer in the area between the northern edge of the Chenango Valley State Park and the Village of Greene. The unconfined aquifer consists predominantly of alluvial and outwash sand and gravel. The water table was mapped using water-level measurements obtained from wells completed in the unconfined aquifer, and from altitudes of lakes, ponds, and streams as indicated on U.S. Geological Survey 1:24,000-scale topographic maps. The depth to the water table typically ranges from 5 to 15 feet below land surface, but can locally be as much as 100 feet, such as in the ice-contact deposits in the Chenango Valley State Park.The confined aquifer is widely used by people living and working in the Chenango River valley. The confined aquifer consists of ice-contact sand and gravel, typically overlies bedrock, and underlies a confining unit consisting of lacustrine fine sand, silt, and clay. The confining unit is typically more than 100 feet thick in the central parts of the valley between Greene Landing Field and along the northern edge of the Chenango Valley State Park. The thickness of the confined aquifer is more than 40 feet near the Greene Landing Field.
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