Hygromorph artificial muscles are attractive as self-powered actuators driven by moisture from the ambient environment. Previously reported hygromorph muscles have been largely limited to bending or torsional motions or as tensile actuators with low work and energy densities. Herein, we developed a hybrid yarn artificial muscle with a unique coiled and wrinkled structure, which can be actuated by either changing relative humidity or contact with water. The muscle provides a large tensile stroke (up to 78%) and a high maximum gravimetric work capacity during contraction (2.17 kJ kg−1), which is over 50 times that of the same weight human muscle and 5.5 times higher than for the same weight spider silk, which is the previous record holder for a moisture driven muscle. We demonstrate an automatic ventilation system that is operated by the tensile actuation of the hybrid muscles caused by dew condensing on the hybrid yarn. This self-powered humidity-controlled ventilation system could be adapted to automatically control the desired relative humidity of an enclosed space.
Two-dimensional
(2D) layered catalysts have been considered as
a class of ideal catalysts for hydrogen evolution reaction (HER) because
of their abundant active sites with almost zero Gibbs energy change
for hydrogen adsorption. Despite the promising performance, the design
of stable and economic electrochemical catalyst based on 2D materials
remains to be resolved for industrial-scale hydrogen production. Here,
we report layered platinum tellurides, mitrofanovite Pt3Te4, which serves as an efficient and stable catalyst
for HER with an overpotential of 39.6 mV and a Tafel slope of 32.7
mV/dec together with a high current density exceeding 7000 mA/cm2. Pt3Te4 was synthesized as nanocrystals
on a metallic molybdenum ditelluride (MoTe2) template by
a rapid electrochemical method. X-ray diffraction and high-resolution
transmission microscopy revealed that the Pt3Te4 nanocrystals have a unique layered structure with repeated monolayer
units of PtTe and PtTe2. Theoretical calculations exhibit
that Pt3Te4 with numerous edges shows near-zero
Gibbs free-energy change of hydrogen adsorption, which shows the excellent
HER performance as well as the extremely large exchange current density
for massive hydrogen production.
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